5-羟甲基糠醛无碱有氧氧化合成2,5-呋喃二甲酸负载型贵金属催化剂的研究进展

doi:10.16085/j.issn.1000-6613.2020-1677

化工进展 ›› 2021, Vol. 40 ›› Issue (7): 3760-3771.DOI: 10.16085/j.issn.1000-6613.2020-1677

5-羟甲基糠醛无碱有氧氧化合成2,5-呋喃二甲酸负载型贵金属催化剂的研究进展

于雪¹(), 包青青², 高爽³, 张跃伟²()

^1.吉林化工学院科学技术处，吉林吉林 132022
^2.吉林化工学院化学与制药工程学院，吉林吉林 132022
^3.营口理工学院化学与环境工程学院，辽宁营口 115000

收稿日期:2020-08-21 修回日期:2020-12-07 出版日期:2021-07-06 发布日期:2021-07-19
通讯作者: 张跃伟
作者简介:于雪（1987—），女，副教授，博士，研究方向为生物质催化转化。E-mail：dongjibinghuayuxue@163.com。
基金资助:
吉林省教育厅“十三五”科学技术项目(JJKH20200242KJ);吉林市科技创新发展计划(201750231);吉林化工学院校级重大科研项目(2016004);吉林化工学院博士启动基金(2017007);吉林化工学院校级一般科研项目(2017011);辽宁省自然科学基金指导计划(20180550148)

Research progresses on supported precious metal catalysts for base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

YU Xue¹(), BAO Qingqing², GAO Shuang³, ZHANG Yuewei²()

^1.Division of Science and Technology, Jilin Institute Chemical Technology, Jilin 132022, Jilin, China
^2.School of Chemistry and Pharmaceutical Engineering, Jilin Institute Chemical Technology, Jilin 132022, Jilin, China
^3.Department of Chemical and Environmental Engineering, Yingkou Institute of Technology, Yingkou 115000, Liaoning, China

Received:2020-08-21 Revised:2020-12-07 Online:2021-07-06 Published:2021-07-19
Contact: ZHANG Yuewei

摘要/Abstract

摘要：

将生物质平台分子5-羟甲基糠醛（5-hydroxymethylfurfural，HMF）高效、绿色地催化转化为更高附加值的2,5-呋喃二甲酸（2,5-furandicarboxylic acid，FDCA）已经成为目前生物质能源转化领域的研究热点。碱性载体负载贵金属催化剂用于HMF无碱氧化为FDCA已经得到广泛研究，并取得了一系列成果。本文综述了水滑石、羟基磷灰石、碳材料、金属氧化物等不同载体负载的贵金属催化剂用于HMF无碱氧化为FDCA的最新进展，详细介绍了各类催化剂的结构性质、催化反应参数及催化活性，重点讨论了催化剂与催化反应的构效关系及催化反应机理等研究工作。最后，指出了今后在HMF转化为FDCA的研究工作中负载型贵金属催化剂的设计开发及机理探究等方面的努力方向。

关键词: 5-羟甲基糠醛, 2,5-呋喃二甲酸, 无碱, 催化剂, 氧化

Abstract:

The efficient and green catalytic conversion of 5-hydroxymethylfurfural (HMF) into higher value-added 2,5-furandicarboxylic acid (FDCA) has become a research hotspot in the field of biomass energy conversion. The basic carrier supported precious metal catalysts for the base-free aerobic oxidation of HMF to FDCA have been extensively studied, and a series of results have been achieved. In this paper, the latest developments of hydrotalcite, hydroxyapatite, carbon materials, metal oxides and other carrier-supported noble metal catalysts for the base-free aerobic oxidation of HMF to FDCA are reviewed. The structure, properties, catalytic reaction parameters and catalytic activity for different catalysts are introduced. Moreover, the structure-activity relationship and the catalytic reaction mechanism are discussed. Finally, the future directions of the design and development of supported noble metal catalysts and mechanism exploration are pointed out for converting HMF to FDCA.

Key words: 5-hydroxymethylfurfural, 2,5-furandicarboxylic acid, base-free, catalysts, oxidation

中图分类号:

O643

于雪, 包青青, 高爽, 张跃伟. 5-羟甲基糠醛无碱有氧氧化合成2,5-呋喃二甲酸负载型贵金属催化剂的研究进展[J]. 化工进展, 2021, 40(7): 3760-3771.

YU Xue, BAO Qingqing, GAO Shuang, ZHANG Yuewei. Research progresses on supported precious metal catalysts for base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid[J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3760-3771.

图/表 11

参考文献 63

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催化剂	反应条件			HMF	FDCA	参考文献
催化剂	温度/℃	氧化剂，压力/MPa	反应时间/h	转化率/%	产率/%	参考文献
Ru/MgO	160	O₂, 0.62	4	100	90以上	［15］
Pt/C-O-Mg	110	O₂, 1	12	99以上	97	［4］
Au/MgF₂-MgO	110	O₂, 2.6	2	98	64	［11］
xPd-HT-n	100	O₂流（100mL/min）	8	100	99.9	［21］
Au/HT	95	O₂, 常压	7	100	99	［22］
AuPd/La-CaMgAl-LDH	100	O₂, 0.5	6	96	85	［23］
Au/HT-AC	100	O₂, 0.5	12	100	100	［19］
Ru/HAP	120	O₂, 1	24	100	99.6	［24］

催化剂	反应条件			HMF	FDCA	参考文献
催化剂	温度/℃	氧化剂，压力/MPa	反应时间/h	转化率/%	产率/%	参考文献
Ru/MgO	160	O₂, 0.62	4	100	90以上	［15］
Pt/C-O-Mg	110	O₂, 1	12	99以上	97	［4］
Au/MgF₂-MgO	110	O₂, 2.6	2	98	64	［11］
xPd-HT-n	100	O₂流（100mL/min）	8	100	99.9	［21］
Au/HT	95	O₂, 常压	7	100	99	［22］
AuPd/La-CaMgAl-LDH	100	O₂, 0.5	6	96	85	［23］
Au/HT-AC	100	O₂, 0.5	12	100	100	［19］
Ru/HAP	120	O₂, 1	24	100	99.6	［24］

催化剂	反应条件			HMF	FDCA	参考文献
催化剂	温度/℃	氧化剂，压力/MPa	反应时间/h	转化率/%	产率/%	参考文献
AuPd/CNT	100	O₂, 0.5	12	100	96	［8］
Pt/C-EDA-4.1	110	O₂, 1	12	99以上	96	［36］
Pt/Fe₃O₄/rGO	95	O₂, 0.5	9	100	99	［37］
Ru/NrGO	100	空气, 1	8	100	79.6	［38］

催化剂	反应条件			HMF	FDCA	参考文献
催化剂	温度/℃	氧化剂，压力/MPa	反应时间/h	转化率/%	产率/%	参考文献
AuPd/CNT	100	O₂, 0.5	12	100	96	［8］
Pt/C-EDA-4.1	110	O₂, 1	12	99以上	96	［36］
Pt/Fe₃O₄/rGO	95	O₂, 0.5	9	100	99	［37］
Ru/NrGO	100	空气, 1	8	100	79.6	［38］

催化剂	反应条件			HMF	FDCA	参考文献
催化剂	温度/℃	氧化剂，压力/MPa	反应时间/h	转化率/%	产率/%	参考文献
CaMn₂O₄	100	O₂流（100mL/min）	12	100	96.8	［41］
Ru/Mn₆Ce₁O_y	150	O₂, 1	15	100	99	［42］
Ru_xCoO_y（OH）	140	O₂, 1	18	100	99.9	［43］
Ru/MnCo₂O₄	120	空气, 2.4	10	100	99.1	［44］
Pt/ZrO₂	100	O₂, 0.4	12	100	97.3	［45］
Ru/ZrO₂	120	O₂, 1	16	100	97	［46］
PtSn/TiO₂	110	O₂, 1	4	68	13	［47］
AuPd/NiO	90	O₂, 1	6	95	70	［48］
Pt/NC-CeO₂	110	O₂, 4	8	100	100	［49］

5-羟甲基糠醛无碱有氧氧化合成2,5-呋喃二甲酸负载型贵金属催化剂的研究进展

Research progresses on supported precious metal catalysts for base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

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