水驱油藏聚乙烯亚胺交联聚合物凝胶体系研究进展

doi:10.16085/j.issn.1000-6613.2023-0376

化工进展 ›› 2024, Vol. 43 ›› Issue (3): 1506-1523.DOI: 10.16085/j.issn.1000-6613.2023-0376

• 资源与环境化工 • 上一篇

水驱油藏聚乙烯亚胺交联聚合物凝胶体系研究进展

王凯¹(), 罗明良¹(), 李明忠¹, 黄飞飞², 蒲春生¹, 蒲景阳³, 樊乔¹

^1.中国石油大学（华东）石油工程学院，山东青岛 266580
^2.延安大学石油工程与环境工程学院，陕西延安 716000
^3.中国石油大学（北京）碳中和示范性能源学院，北京 102249

收稿日期:2023-03-13 修回日期:2023-04-12 出版日期:2024-03-10 发布日期:2024-04-11
通讯作者: 罗明良
作者简介:王凯（1995—），男，博士研究生，研究方向为化学法提高采收率。E-mail：13689288083@163.com。
基金资助:
国家自然科学基金(51874334);陕西省自然科学基础研究计划(2023-JC-QN-0540)

Research progress of polyethyleneimine crosslinked polymer gel system in water-drive reservoirs

WANG Kai¹(), LUO Mingliang¹(), LI Mingzhong¹, HUANG Feifei², PU Chunsheng¹, PU Jingyang³, FAN Qiao¹

^1.College of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China
^2.School of Petroleum Engineering and Environmental Engineering, Yan’an University, Yan’an 716000, Shaanxi, China
^3.College of Carbon Neutral Energy, China University of Petroleum (Beijing), Beijing 102249, China

Received:2023-03-13 Revised:2023-04-12 Online:2024-03-10 Published:2024-04-11
Contact: LUO Mingliang

摘要/Abstract

摘要：

聚乙烯亚胺（PEI）是一种低毒性环保材料，它与聚合物交联的凝胶体系具有适用温度范围广、成胶时间可控、成胶后强度大、高温稳定时间长、几乎不受储层岩石矿物影响等优点。本文回顾了以PEI作为交联剂的各类凝胶体系的研究动态，阐明了PEI与各类聚合物的交联反应机理及其凝胶体系特点，分析了各类因素对凝胶性能的影响，并列举了改善凝胶性能的方法和成功的矿场应用实例，重点分析了提高凝胶体系交联活性的方法研究。最后，提出聚丙烯酰胺（PAM）/PEI凝胶体系作为环保型调驱体系在中低温油藏深部调控方面具有非常大的应用前景，应继续深入研究提高PAM/PEI凝胶体系交联效率的方法及其作用机理，以降低聚合物与交联剂用量，为这一体系的推广应用提供理论依据与实验基础。

关键词: 聚合物, 凝胶, 聚乙烯亚胺, 交联剂, 黏度, 调剖堵水

Abstract:

Polyethyleneimine (PEI) is an environment-friendly and low toxic material. PEI and polymer crosslinked gel system has the advantages of controllable gelation time, high strength of mature gel, high-temperature resistance, long-time stability, and almost unaffected by minerals of reservoir. This paper reviewed the research of various polymer gel systems with PEI as crosslinker. The crosslinking mechanism and the characteristics of those gel systems were clarified. The influence of various factors on the gel system was analyzed. And, the methods to improve the gel performance and successful filed trial were listed, the methods to improve the crosslinking activity of gel system were emphatically analyzed. Finally, it was pointed out that polyacrylamide(PAM)/PEI gel system, as an environment-friendly system, had great application prospects in conformance control and water shutoff of medium and low temperature reservoirs, and it was suggested that the method and the corresponding mechanism of improving the crosslinking efficiency of PAM/PEI system should be studied more extensively and deeply to reduce the loading amount of polymer and crosslinker, and provided a theoretical basis and experimental basis for the promotion and application of this system.

Key words: polymers, gels, polyethyleneimine(PEI), crosslinker, viscosity, conformance control and water shutoff

中图分类号:

TE39

王凯, 罗明良, 李明忠, 黄飞飞, 蒲春生, 蒲景阳, 樊乔. 水驱油藏聚乙烯亚胺交联聚合物凝胶体系研究进展[J]. 化工进展, 2024, 43(3): 1506-1523.

WANG Kai, LUO Mingliang, LI Mingzhong, HUANG Feifei, PU Chunsheng, PU Jingyang, FAN Qiao. Research progress of polyethyleneimine crosslinked polymer gel system in water-drive reservoirs[J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1506-1523.

图/表 20

参考文献 95

1	李宜坤, 李宇乡, 彭杨, 等. 中国堵水调剖60年[J]. 石油钻采工艺, 2019, 41(6): 773-787.
	LI Yikun, LI Yuxiang, PENG Yang, et al. Water shutoff and profile control in China over 60 years[J]. Oil Drilling & Production Technology, 2019, 41(6): 773-787.
2	王翔, 郭继香, 陈金梅. 油田深部调剖技术及其应用研究进展[J]. 油田化学, 2020, 37(4): 738-744.
	WANG Xiang, GUO Jixiang, CHEN Jinmei. Research progress of deep profile control technology and its application[J]. Oilfield Chemistry, 2020, 37(4): 738-744.
3	ZHU Daoyi, BAI Baojun, HOU Jirui. Polymer gel systems for water management in high-temperature petroleum reservoirs: A chemical review[J]. Energy & Fuels, 2017, 31(12): 13063-13087.
4	SERIGHT R S. Gel propagation through fractures[J]. SPE Production & Facilities, 2001, 16(4): 225-231.
5	BRYANT Steven L, BARTOSEK Martin, LOCKHART Thomas P, et al. Polymer gelants for high temperature water shutoff applications[J]. SPE Journal, 1997, 2(4): 447-454.
6	BARTOSEK Martin, MENNELLA Aniello, LOCKHART T P, et al. Polymer gels for conformance treatments: Propagation of Cr(III) crosslinking complexes in porous media[C]//Proceedings - SPE/DEO Ninth Symposium on Improved Oil Recovery, 1994, 2: 505-517.
7	ALBONICO Paola, BARTOSEK Martin, MALANDRINO Alberto, et al. Studies on phenol-formaldehyde crosslinked polymer gels in bulk and in porous media[C]//All Days. February 14-17, 1995. San Antonio, Texas. SPE International Symposium on Oilfield Chemistry, 1995.
8	WANG Kai, LUO Mingliang, LI Mingzhong, et al. Optimization of hydrolyzed polyacrylamide/chromium -acetate gel-plugging process after preflush crosslinker in fractured extralow permeability reservoir at moderate temperature[J]. SPE Journal, 2023, 28(2): 683-696.
9	GANGULY S, WILLHITE G P, GREEN D W, et al. The effect of fluid leakoff on gel placement and gel stability in fractures[J]. SPE Journal, 2002, 7(3): 309-315.
10	REDDY B R, EOFF Larry S, CRESPO Freddy, et al. Recent advances in organically crosslinked conformance polymer systems[C]//All Days. April 8-10, 2013. WoodlandsThe, Texas, USA. SPE International Symposium on Oilfield Chemistry, 2013.
11	ANTONIETTI Lydie, AYMONIER Cyril, SCHLOTTERBECK Ulf, et al. Core–shell-structured highly branched poly(ethylenimine amide)s: Synthesis and structure[J]. Macromolecules, 2005, 38(14): 5914-5920.
12	VICENNATI Paola, GIULIANO Antonella, ORTAGGI Giancarlo, et al. Polyethylenimine in medicinal chemistry[J]. Current Medicinal Chemistry, 2008, 15(27): 2826-2839.
13	VIRGEN-ORTÍZ Jose J, DOS SANTOS José C S, Ángel BERENGUER-MURCIA, et al. Polyethylenimine: A very useful ionic polymer in the design of immobilized enzyme biocatalysts[J]. Journal of Materials Chemistry B, 2017, 5(36): 7461-7490.
14	DALRYMPLE E D, EVERETT D, EOFF L. Global field results of a polymeric gel system in conformance applications[C]//SPE Russian Oil and Gas Technical Conference and Exhibition, 2006.
15	AL-MUNTASHERI Ghaithan A, HUSSEIN Ibnelwaleed A, NASR-EL-DIN Hisham A, et al. Viscoelastic properties of a high temperature cross-linked water shut-off polymeric gel[J]. Journal of Petroleum Science and Engineering, 2007, 55(1/2): 56-66.
16	DEOLARTE Carlos, VASQUEZ Julio, SORIANO Eduardo, et al. Successful combination of an organically crosslinked polymer system and a rigid-setting material for conformance control in Mexico[J]. SPE Production & Operations, 2009, 24(4): 522-529.
17	VASQUEZ J, DALRYMPLE E D, EOFF L, et al. Development and evaluation of high-temperature conformance polymer systems[C]//All Days. February 2-4, 2005. The Woodlands, Texas. SPE International Symposium on Oilfield Chemistry, 2005.
18	AL-MUNTASHERI G A, NASR-EL-DIN H A, ZITHA P L J. Gelation kinetics and performance evaluation of an organically crosslinked gel at high temperature and pressure[J]. SPE Journal, 2008, 13(3): 337-345.
19	AL-MUNTASHERI Ghaithan A, SIERRA Leopoldo, BAKHTIYAROV Albert. Ammonium halide as gelation retarder for crosslinkable polymer compositions: US20140224489[P]. 2014-08-14.
20	AL-MUNTASHERI Ghaithan A, SIERRA Leopoldo, GARZON Francisco, et al. Water shut-off with polymer gels in a high temperature horizontal gas well: A success story[C]//All Days. April 24-28, 2010. Tulsa, Oklahoma, USA. SPE Improved Oil Recovery Symposium, 2010.
21	SUN Feifei, LIN Meiqin, DONG Zhaoxia, et al. Nanosilica-induced high mechanical strength of nanocomposite hydrogel for killing fluids[J]. Journal of Colloid and Interface Science, 2015, 458: 45-52.
22	LIU Yifei, DAI Caili, WANG Kai, et al. Study on a novel cross-linked polymer gel strengthened with silica nanoparticles[J]. Energy & Fuels, 2017, 31(9): 9152-9161.
23	DALRYMPLE Dwyann, EOFF Larry, VASQUEZ Julio, et al. Shallow penetration particle-gel system for water and gas shut-off applications (russian)[C]//SPE Russian Oil and Gas Technical Conference and Exhibition. Moscow, Russia. Society of Petroleum Engineers, 2008.
24	ALBONICO Paola, LOCKHART T P. Divalent ion-resistant polymer gels for high-temperature applications: Syneresis inhibiting additives[C]//All Days. March 2-5, 1993. New Orleans, Louisiana. SPE International Symposium on Oilfield Chemistry, 1993.
25	HARDY Mary, BOTERMANS Wouter, HAMOUDA Aly, et al. The first carbonate field application of a new organically crosslinked water shutoff polymer system[C]//All Days. February 16-19, 1999. Houston, Texas. SPE International Symposium on Oilfield Chemistry, 1999.
26	VASQUEZ J, JURADO I, SANTILLAN A, et al. Organically crosslinked polymer system for water reduction treatments in Mexico[C]//All Days. August 31-September 2, 2006. Cancun, Mexico. SPE International Oil Conference and Exhibition, 2006.
27	BAI Baojun, ZHOU Jia, YIN Mingfei. A comprehensive review of polyacrylamide polymer gels for conformance control[J]. Petroleum Exploration and Development, 2015, 42(4): 525-532.
28	JIA Hu, PU Wanfen, ZHAO Jinzhou, et al. Research on the gelation performance of low toxic PEI cross-linking PHPAM gel systems as water shutoff agents in low temperature reservoirs[J]. Industrial & Engineering Chemistry Research, 2010, 49(20): 9618-9624.
29	ALLISON Joe D. Reducing permeability of highly permeable zones in oil and gas formations: US4773482[P]. 1988-09-27.
30	AL-MUNTASHERI Ghaithan A, NASR-EL-DIN Hisham A, HUSSEIN Ibnelwaleed A. A rheological investigation of a high temperature organic gel used for water shut-off treatments[J]. Journal of Petroleum Science and Engineering, 2007, 59(1/2): 73-83.
31	SYDANSK Robert D, ARGABRIGHT Perry A. Conformance improvement in a subterranean hydrocarbon-bearing formation using a polymer gel: US4683949[P]. 1987-08-04.
32	MORTIMER S, RYAN A J, STANFORD J L. Rheological behavior and gel-point determination for a model lewis acid-initiated chain growth epoxy resin[J]. Macromolecules, 2001, 34(9): 2973-2980.
33	AL-MUNTASHERI Ghaithan A, NASR-EL-DIN Hisham A, AL-NOAIMI Khalid R, et al. A study of polyacrylamide-based gels crosslinked with polyethyleneimine[J]. SPE Journal, 2009, 14(2): 245-251.
34	VASQUEZ J E, EOFF L. Laboratory development and successful field application of a conformance polymer system for low-, medium-, and high-temperature applications[C]//All Days. December 1-3, 2010. Lima, Peru. SPE Latin American and Caribbean Petroleum Engineering Conference, 2010.
35	REDDY B R, EOFF Larry, DALRYMPLE E Dwyann, et al. A natural polymer-based cross-linker system for conformance gel systems[J]. SPE Journal, 2003, 8(2): 99-106.
36	AL-MUNTASHERI Ghaithan A, NASR-EL-DIN Hisham A, PETERS Joop, et al. Investigation of a high temperature organic water shutoff gel: Reaction mechanisms[J]. SPE Journal, 2006, 11(4): 497-504.
37	DALRYMPLE E D, EOFF L, REDDY B R, et al. Studies of a relative permeability modifier treatment performed using multitap flow cells[C]//All Days. April 3-5, 2000. Tulsa, Oklahoma. SPE/DOE Improved Oil Recovery Symposium, 2000.
38	AL-MUNTASHERI Ghaithan A, NASR-EL-DIN Hisham A, PETERS Joop, et al. Investigation of a high temperature organic water shutoff gel: Reaction mechanisms[J]. SPE Journal, 2006, 11(4): 497-504.
39	LIU Jin, SERIGHT R S. Rheology of gels used for conformance control in fractures[J]. SPE Journal, 2001, 6(2): 120-125.
40	ZITHA Pacelli L J, Wouter BOTERMANS C, HOEK Jeroen V D, et al. Control of flow through porous media using polymer gels[J]. Journal of Applied Physics, 2002, 92(2): 1143-1153.
41	WANG Demin, CHENG Jiecheng, WU Junzheng, et al. Producing by polymer flooding more than 300 million barrels of oil, what experiences have been learnt? [C]//All Days. October 8-10, 2002. Melbourne, Australia. SPE Asia Pacific Oil and Gas Conference and Exhibition, 2002.
42	ZHAO Jinzhou, JIA Hu, PU Wanfen, et al. Influences of fracture aperture on the water-shutoff performance of polyethyleneimine cross-linking partially hydrolyzed polyacrylamide gels in hydraulic fractured reservoirs[J]. Energy & Fuels, 2011, 25(6): 2616-2624.
43	JIA Hu, ZHAO Jinzhou, JIN Fayang, et al. New insights into the gelation behavior of polyethyleneimine cross-linking partially hydrolyzed polyacrylamide gels[J]. Industrial & Engineering Chemistry Research, 2012, 51(38): 12155-12166.
44	SUH J, PAIK H J, HWANG B K. Ionization of poly(ethylenimine) and poly(allylamine) at various pH’s[J]. Bioorganic Chemistry, 1994, 22(3): 318-327.
45	RABIEE A. Acrylamide-based anionic polyelectrolytes and their applications: A survey[J]. Journal of Vinyl and Additive Technology, 2010, 16(2): 111-119.
46	EL-KARSANI Khalid S M, AL-MUNTASHERI Ghaithan A, SULTAN Abdullah S, et al. Gelation of a water-shutoff gel at high pressure and high temperature: Rheological investigation[J]. SPE Journal, 2015, 20(5): 1103-1112.
47	AL-MUNTASHERI Ghaithan A, ZITHA Pacelli L J. Gel under Dynamic Stress in Porous Media: New Insights using Computed Tomography[C]//All Days. May 9-11, 2009. Al-Khobar, Saudi Arabia. SPE Saudi Arabia Section Technical Symposium, 2009.
48	MOHAMED Abdelhalim I A, HUSSEIN Ibnelwaleed A, SULTAN Abdullah S, et al. DSC investigation of the gelation kinetics of emulsified PAM/PEI system[J]. Journal of Thermal Analysis and Calorimetry, 2015, 122(3): 1117-1123.
49	MOHAMED Abdelhalim I A, HUSSEIN Ibnelwaleed A, SULTAN Abdullah S, et al. Gelation of emulsified polyacrylamide/polyethylenimine under high-temperature, high-salinity conditions: Rheological investigation[J]. Industrial & Engineering Chemistry Research, 2018, 57(36): 12278-12287.
50	REDDY B R, CRESPO Freddy, EOFF Larry. Water shutoff at ultralow temperatures using organically crosslinked polymer gels[C]//All Days. April 14-18, 2012. Tulsa, Oklahoma, USA. SPE Improved Oil Recovery Symposium, 2012.
51	BROSETA D, MARQUER O, BLIN N, et al. Rheological screening of low-molecular-weight polyacrylamide/chromium(Ⅲ) acetate water shutoff gels[C]//All Days. April 3-5, 2000. Tulsa, Oklahoma. SPE/DOE improved oil recovery symposium, 2000.
52	ZHU Daoyi, HOU J, CHEN Yuguang, et al. Evaluation of terpolymer-gel systems crosslinked by polyethylenimine for conformance improvement in high-temperature reservoirs[J]. SPE Journal, 2019, 24(4): 1726-1740
53	KARSANI Khalid S M EL, AL-MUNTASHERI Ghaithan A, SULTAN Abdullah S, et al. Impact of salts on polyacrylamide hydrolysis and gelation: New insights[J]. Journal of Applied Polymer Science, 2014, 131(23): 41185.
54	HASHMAT M D, SULTAN Abdullah S, RAHMAN Saifur, et al. Crosslinked polymeric gels as loss circulation materials: An experimental study[C]//All Days. April 25-28, 2016. Dammam, Saudi Arabia. SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, 2016.
55	VASQUEZ J, CIVAN F, SHAW T, et al. Laboratory evaluation of high-temperature conformance olymer systems[C]//SPE Production and Operations Symposium, 2003
56	QIN Yi, LIAO Ruiquan, LUO Shunshe, et al. The thermal gelation behavior and performance evaluation of high molecular weight nonionic polyacrylamide and polyethyleneimine mixtures for In-depth water control in mature oilfields[J]. Materials, 2020, 13(18): 4142.
57	BAI Yingrui, XIONG C, WEI F, et al. Gelation study on a hydrophobically associating polymer/polyethylenimine gel system for water shut-off treatment[J]. Energy & Fuels, 2015, 29: 447-458.
58	GHRIGA Mohammed Abdelfetah, GARECHE Mourad, KHODJA Mohamed, et al. Structure-property relationships of the thermal gelation of partially hydrolyzed polyacrylamide/polyethylenimine mixtures in a semidilute regime[J]. Polymer Bulletin, 2020, 77(3): 1465-1488.
59	GHRIGA Mohammed Abdelfetah, GRASSL Bruno, GARECHE Mourad, et al. Review of recent advances in polyethylenimine crosslinked polymer gels used for conformance control applications[J]. Polymer Bulletin, 2019, 76(11): 6001-6029.
60	GALES J R, YOUNG T S, WILLHITE G P, et al. Equilibrium swelling and syneresis properties of xanthan gum/Cr(Ⅲ) gels[J]. SPE Advanced Technology Series, 1994, 2(2): 190-198.
61	KARIMI Shahram, KAZEMI Shabnam, KAZEMI Neda. Syneresis measurement of the HPAM-Cr(Ⅲ) gel polymer at different conditions: An experimental investigation[J]. Journal of Natural Gas Science and Engineering, 2016, 34: 1027-1033.
62	HATZIGNATIOU Dimitrios G, GISKE Nils H, STAVLAND Arne. Polymers and polymer-based gelants for improved oil recovery and water control applications in naturally fractured chalk formations[C]//Day 1 Wed, April 20, 2016. April 20, 2016. Grieghallen, Bergen, Norway. SPE Bergen One Day Seminar,, 2016.
63	HASANKHANI Ghodsieh Moosa, MADANI Mohammad, ESMAEILZADEH Feridun, et al. An experimental investigation of polyacrylamide and sulfonated polyacrylamides based gels crosslinked with Cr -acetate for water shutoff in fractured oil reservoirs[J]. Journal of Dispersion Science and Technology, 2018, 39(12): 1780-1789.
64	AL-MUNTASHERI G A, NASR-EL-DIN H A, ZITHA P L J. Gelation kinetics of an organically cross-linked gel at high temperature and pressure[C]//All Days. August 31-September 2, 2006. Cancun, Mexico. SPE International Oil Conference and Exhibition, 2006.
65	CORDOVA Mary, CHENG Min, TREJO Julieta, et al. Delayed HPAM gelation via transient sequestration of chromium in polyelectrolyte complex nanoparticles[J]. Macromolecules, 2008, 41(12): 4398-4404.
66	CRESPO F, REDDY B R, EOFF L, et al. Development of a polymer gel system for improved sweep efficiency and injection profile modification of IOR/EOR treatments[C]//IPTC 2014: International Petroleum Technology Conference. Doha, Qatar, European Association of Geoscientists & Engineers, 2014.
67	CHEN Jiajia, XIA Yuanzhi, LEE Sunwoo. Transamidation for the synthesis of primary amides at room temperature[J]. Organic Letters, 2020, 22(9): 3504-3508.
68	赵梦云, 张锁兵, 丁树柏, 等. 高温稳定剪切条件下聚乙烯亚胺冻胶成胶性能研究[J]. 油田化学, 2010, 27(1): 69-72, 15.
	ZHAO Mengyun, ZHANG Suobing, DING Shubai, et al. Gelation of polyethyleneimine gelling fluid under high temperature and steady shear conditions[J]. Oilfield Chemistry, 2010, 27(1): 69-72, 15.
69	EL-KARSANI Khalid S M, AL-MUNTASHERI Ghaithan A, SULTAN Abdullah S, et al. Gelation kinetics of PAM/PEI system[J]. Journal of Thermal Analysis and Calorimetry, 2014, 116(3): 1409-1415.
70	JIA Hu, CHEN Hao. Using DSC technique to investigate the non-isothermal gelation kinetics of the multi-crosslinked Chromium acetate (Cr³⁺)-Polyethyleneimine (PEI)-Polymer gel sealant[J]. Journal of Petroleum Science and Engineering, 2018, 165: 105-113.
71	ZHAO Guang, DAI Caili, YOU Qing, et al. Study on formation of gels formed by polymer and zirconium acetate[J]. Journal of Sol-Gel Science and Technology, 2013, 65(3): 392-398.
72	UDDIN F, SHAHID N, TAHIR H. Salt effects on the reaction rates of ethyloxalate with hydroxide ions in the presence of sodium and potassium sulfate[J]. Arabian Journal for Science and Engineering, 2002, 27(2): 163-172.
73	JIA H, REN Q. Evidence of the gelation acceleration mechanism of HPAM gel with ammonium salt at ultralow temperature by SEM study[J]. SPE Production & Operations, 2016, 31(3): 238-246.
74	SANTOS Allan S, OLIVEIRA Luis Fernando S, MARQUES Anny M T, et al. Evaluation of the efficiency of polyethylenimine as flocculants in the removal of oil present in produced water[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 558: 200-210.
75	GHRIGA Mohammed Abdelfetah, HASANZADEH Mahdi, GARECHE Mourad, et al. Thermal gelation of partially hydrolysed polyacrylamide/polyethylenimine mixtures using design of experiments approach[J]. Materials Today Communications, 2019, 21: 100686.
76	WANG Lizhu, LONG Yifu, BAI Baojun. Low temperature applicable polyelectrolyte gelator to covalently bridged partially hydrolyzed poly(acrylamide) in situ gel for fossil energy recovery[J]. Chemical Engineering Journal, 2018, 334: 2558-2567.
77	QIN Yi, CHENG Li, ZHANG Manlai, et al. Dynamic thickening investigation of the gelation process of PAM/PEI system at high temperature and high pressure[J]. Journal of Dispersion Science and Technology, 2017, 38(11): 1640-1646.
78	贾艳平, 王业飞, 何龙, 等. 堵剂聚乙烯亚胺冻胶成冻影响因素研究[J]. 油田化学, 2007, 24(4): 316-319.
	JIA Yanping, WANG Yefei, HE Long, et al. Influencing factors for polyacrylamide/polyethyleneimine gelling fluid as water shutoff/profile modification agent[J]. Oilfield Chemistry, 2007, 24(4): 316-319.
79	MORGAN J C, SMITH P L, STEVENS D G. Chemical Adaptation and Deployment Strategies for Water and Gas Shut-off Gel Systems[J]. Special Publication. Royal Society of Chemistry, 1998, 211: 119-131.
80	EOFF L, DALRYMPLE D, EVERETT D, et al. Worldwide field applications of a polymeric gel system for conformance applications[J]. SPE Production & Operations, 2007, 22(2): 231-235.
81	AMIR Zulhelmi, MOHD SAAID Ismail, MOHAMED JAN Badrul, et al. Gelation performance of PAM/PEI polymer gel with addition of retarder in high-salinity conditions[J]. Journal of Sol-Gel Science and Technology, 2022, 101(1): 299-313.
82	刘锦霞, 赵梦云, 赵青. 高温下PAM/PEI体系延缓成胶技术研究[J]. 油田化学, 2010, 27(3): 279-283.
	LIU Jinxia, ZHAO Mengyun, ZHAO Qing. Delayed gelation of polyacrylamide/modified polyethyleneimine aqueous system at high temperatures[J]. Oilfield Chemistry, 2010, 27(3): 279-283.
83	秦义, 石峥, 刘玉莉, 等. PAM/PEI凝胶成胶时间影响因素分析[J]. 现代化工, 2017, 37(9): 95-98.
	QIN Yi, SHI Zheng, LIU Yuli, et al. Analysis on influence factors on gelation time of PAM/PEI gel system[J]. Modern Chemical Industry, 2017, 37(9): 95-98.
84	PENG Baoliang, TANG Juntao, LUO Jianhui, et al. Applications of nanotechnology in oil and gas industry: Progress and perspective[J]. The Canadian Journal of Chemical Engineering, 2018, 96(1): 91-100.
85	FAKOYA Muili Feyisitan, SHAH Subhash Nandlal. Emergence of nanotechnology in the oil and gas industry: Emphasis on the application of silica nanoparticles[J]. Petroleum, 2017, 3(4): 391-405.
86	JAYAKUMAR Swathika, LANE Robert H. Delayed crosslink polymer flowing gel system for water shutoff in conventional and unconventional oil and gas reservoirs[C]//All Days. February 15-17, 2012. Lafayette, Louisiana, USA. SPE International Symposium and Exhibition on Formation Damage Control, 2012.
87	JAYAKUMAR Swathika, LANE Robert H. Delayed crosslink polymer gel system for water shutoff in conventional and unconventional oil and gas reservoirs[C]//SPE International Symposium on Oilfield Chemistry. The Woodlands, Texas, USA. Society of Petroleum Engineers, 2013.
88	CHEN Lifeng, WANG Jinjie, YU Long, et al. Experimental investigation on the nanosilica-reinforcing polyacrylamide/polyethylenimine hydrogel for water shutoff treatment[J]. Energy & Fuels, 2018, 32(6): 6650-6656.
89	李强, 于小荣, 肖雪, 等. 纳米SiO₂增强PAM/PEI冻胶的制备及性能[J]. 精细化工, 2021, 38(1): 200-205.
	LI Qiang, YU Xiaorong, XIAO Xue, et al. Preparation and properties of nanosilica-reinforced PAM/PEI gels[J]. Fine Chemicals, 2021, 38(1): 200-205.
90	VAN EIJDEN Jip, ARKESTEIJN Fred, AKIL Ihab, et al. Gel-cement, a water shut-off system: Qualification in a Syrian field[C]//All Days. October 10-13, 2004. Abu Dhabi, United Arab Emirates. SPE International Conference and Exhibition, 2004.
91	HERNANDEZ R, VASQUEZ J, CANCINO V, et al. Successful water-shutoff case histories in a naturally fractured carbonate reservoir in offshore Mexico using an organically crosslinked polymer system with a modified tail-In[C]//All Days. February 10-12, 2010. Lafayette, Louisiana, USA. SPE International Symposium and Exhibition on Formation Damage Control, 2010.
92	MERCADO M, ACUNA J C, NAJERA D, et al. High-temperature water control with an organically crosslinked polymer-case histories from Mexico[C]//All Days. May 31-June 30, 2009. Cartagena de Indias, Colombia. SPE/Latin American and Caribbean Petroleum Engineering Conference, 2009.
93	贾虎, 蒲万芬. 有机凝胶控水及堵水技术研究[J]. 西南石油大学学报(自然科学版), 2013, 35(6): 141-152.
	JIA Hu, PU Wanfen. Research on water control and water shutoff technologies of organic-gel[J]. Journal of Southwest Petroleum University (Science & Technology Edition), 2013, 35(6): 141-152.
94	MCGOWEN Mary A Hardy, BARRETT Emile, DEDIGAMA Thivanka, et al. Reducing water rates to increase hydrocarbon rates in Australia[C]//All Days. May 27-29, 2009. Scheveningen, The Netherlands. SPE European Formation Damage Conference, 2009.
95	ADEWUNMI Ahmad A, ISMAIL Suzylawati, SULTAN Abdullah S. Crosslinked polyacrylamide composite hydrogels impregnated with fly ash: Synthesis, characterization and their application as fractures sealant for high water producing zones in oil and gas wells[J]. Journal of Polymers and the Environment, 2018, 26(8): 3294-3306.

聚合物质量分数	分子量/10⁶g·mol^-1，HD/%	PEI质量分数 /%	分子量/10⁶ g·mol^-1，分枝度/%	初始黏度 /mPa·s	温度 /℃	成胶时间 /h	矿化度 /g·L^-1	参考文献
0.5% HPAM	M_w=5.1，HD=6.1	0.1	，；，	—	80	2~3	3.4	[58]
1%~2% HPAM	M_w=4~12，HD≤10	0.2~0.35	M_w=0.02	617	65	4~72	0.5	[53]
0.5%~1.5% HPAM	M_w=2~8，HD≤10	0.2~1.5	M_w=0.02	—	40	15~216	90	[28]
2% Alcomer130%/7% HPAM	M_w=0.25~0.5，HD≤7~57.8	0.3	M_w=0.07	—	120	0.5~0.75	—	[34]
2% HPAM	M_w=8，HD≤10	0.35	M_w=0.02	409	65	10	5	[53]
5% HPAM	—	0.33~3	—	—	25	8~13	0.2（KCl）	[34]
					60	1.5~6
0.75% HPAM	M_w=15，HD≤8	0.41	—	33	85	3	0.2（KCl）	[66]
3% HPAM	M_w=8，HD≤25~30	0.6~1.2	—	—	100	3.3	去离子水	[54]
3.5% HPAM	M_w=5~13，HD≤5~8	1	—	—	71.1	2.5	0.2（KCl）	[10]

聚合物质量分数	分子量/10⁶g·mol^-1，HD/%	PEI质量分数 /%	分子量/10⁶ g·mol^-1，分枝度/%	初始黏度 /mPa·s	温度 /℃	成胶时间 /h	矿化度 /g·L^-1	参考文献
0.5% HPAM	M_w=5.1，HD=6.1	0.1	，；，	—	80	2~3	3.4	[58]
1%~2% HPAM	M_w=4~12，HD≤10	0.2~0.35	M_w=0.02	617	65	4~72	0.5	[53]
0.5%~1.5% HPAM	M_w=2~8，HD≤10	0.2~1.5	M_w=0.02	—	40	15~216	90	[28]
2% Alcomer130%/7% HPAM	M_w=0.25~0.5，HD≤7~57.8	0.3	M_w=0.07	—	120	0.5~0.75	—	[34]
2% HPAM	M_w=8，HD≤10	0.35	M_w=0.02	409	65	10	5	[53]
5% HPAM	—	0.33~3	—	—	25	8~13	0.2（KCl）	[34]
					60	1.5~6
0.75% HPAM	M_w=15，HD≤8	0.41	—	33	85	3	0.2（KCl）	[66]
3% HPAM	M_w=8，HD≤25~30	0.6~1.2	—	—	100	3.3	去离子水	[54]
3.5% HPAM	M_w=5~13，HD≤5~8	1	—	—	71.1	2.5	0.2（KCl）	[10]

名称	化学结构	pK_a1	pK_a2	pK_a3	pK_a4	pK_a5
聚乙烯亚胺（PEI）	(CH₂CH₂NH) _n	4.5	6.7	11.6	—	—
低聚多胺
乙二胺（EDA）	H₂N-CH₂-CH₂-NH₂	7.56	10.7	—	—	—
二乙烯三胺（DETA）	H₂N-CH₂-CH₂-NH-CH₂-CH₂-NH₂	4.42	9.21	10.02	—	—
三乙烯四胺（TETA）	H₂N-(CH₂-CH₂-NH)₂-CH₂-CH₂-NH₂	3.32	6.67	9.2	9.92	—
四乙烯五胺（TEPA）	H₂N-(CH₂-CH₂-NH₂)₂-CH₂-CH₂-NH₂	2.98	4.72	9.18	9.18	9.68
烷醇胺
乙醇胺（EA）	HO-CH₂-CH₂-HN₂	9.44	—	—	—	—
二乙醇胺（DEA）	(HO-CH₂-CH₂)₂NH	8.5	—	—	—	—
三乙醇胺（TEA）	(HO-CH₂-CH₂)₃N	7.8	—	—	—	—

名称	化学结构	pK_a1	pK_a2	pK_a3	pK_a4	pK_a5
聚乙烯亚胺（PEI）	(CH₂CH₂NH) _n	4.5	6.7	11.6	—	—
低聚多胺
乙二胺（EDA）	H₂N-CH₂-CH₂-NH₂	7.56	10.7	—	—	—
二乙烯三胺（DETA）	H₂N-CH₂-CH₂-NH-CH₂-CH₂-NH₂	4.42	9.21	10.02	—	—
三乙烯四胺（TETA）	H₂N-(CH₂-CH₂-NH)₂-CH₂-CH₂-NH₂	3.32	6.67	9.2	9.92	—
四乙烯五胺（TEPA）	H₂N-(CH₂-CH₂-NH₂)₂-CH₂-CH₂-NH₂	2.98	4.72	9.18	9.18	9.68
烷醇胺
乙醇胺（EA）	HO-CH₂-CH₂-HN₂	9.44	—	—	—	—
二乙醇胺（DEA）	(HO-CH₂-CH₂)₂NH	8.5	—	—	—	—
三乙醇胺（TEA）	(HO-CH₂-CH₂)₃N	7.8	—	—	—	—

[1]	刘萌萌, 秋列维, 万智卫, 李世婧, 许玉雨. 自愈水凝胶的设计原理及应用[J]. 化工进展, 2024, 43(3): 1350-1362.
[2]	王雄, 康文倩, 任悦, 乔彤森, 张鹏, 黄安平, 李广全. 多孔有机聚合物中试制备及其在聚烯烃催化剂中的应用[J]. 化工进展, 2024, 43(3): 1412-1417.
[3]	钱俊明, 郭猛, 任秀秀, 余亮, 钟璟, 徐荣. 芳烃官能化有机硅膜的制备及丙烯/丙烷分离性能[J]. 化工进展, 2024, 43(3): 1428-1435.
[4]	刘泽鹏, 曾纪珺, 唐晓博, 赵波, 韩升, 廖袁淏, 张伟. 四种烷基咪唑磷酸酯离子液体的热力学性质[J]. 化工进展, 2024, 43(3): 1484-1491.
[5]	王岩森, 侯丹丹, 李长金, 祁丽亚, 王春堯, 郭敏, 王颖. 氧化石墨烯/聚丙烯酸基导电黏附凝胶的制备与性能[J]. 化工进展, 2024, 43(2): 1022-1032.
[6]	剧芳. 基于银-硫配位的协同抗菌水凝胶的制备与性能[J]. 化工进展, 2024, 43(2): 1039-1046.
[7]	刘泽鹏, 曾纪珺, 廖袁淏, 唐晓博, 赵波, 韩升, 张伟. 离子液体1-乙基-3-甲基咪唑亚磷酸甲酯盐与1-乙基-3-甲基咪唑亚磷酸乙酯盐的热物性[J]. 化工进展, 2024, 43(2): 1054-1062.
[8]	于笑笑, 巢艳红, 刘海燕, 朱文帅, 刘植昌. D-A共轭聚合强化光电性能及光催化CO₂转化[J]. 化工进展, 2024, 43(1): 292-301.
[9]	孙月, 王斯佳, 吴明侠, 宋先雨, 徐首红. pH/温度响应型聚合物PMAA-b-PDMAEMA的合成、性能调控及应用[J]. 化工进展, 2024, 43(1): 480-489.
[10]	林晓鹏, 肖友华, 管奕琛, 鲁晓东, 宗文杰, 傅深渊. 离子聚合物-金属复合材料（IPMC）柔性电极的研究进展[J]. 化工进展, 2023, 42(9): 4770-4782.
[11]	王少凡, 周颖, 郝康安, 黄安荣, 张如菊, 吴翀, 左晓玲. 具有pH响应性的自愈合蓝光水凝胶[J]. 化工进展, 2023, 42(9): 4837-4846.
[12]	朱传强, 茹晋波, 孙亭亭, 谢兴旺, 李长明, 高士秋. 固体高分子脱硝剂选择性非催化还原NO _x 特性[J]. 化工进展, 2023, 42(9): 4939-4946.
[13]	李伯耿, 罗英武, 刘平伟. 聚合物产品工程研究内容与方法的思考[J]. 化工进展, 2023, 42(8): 3905-3909.
[14]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[15]	张婷婷, 潘大伟, 巨晓洁, 刘壮, 谢锐, 汪伟, 褚良银. Hg²⁺响应型智能凝胶检测光栅的构建与性能[J]. 化工进展, 2023, 42(8): 4143-4152.

水驱油藏聚乙烯亚胺交联聚合物凝胶体系研究进展

Research progress of polyethyleneimine crosslinked polymer gel system in water-drive reservoirs

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 20

参考文献 95

相关文章 15

编辑推荐

Metrics

本文评价