化工进展
Home |  |  |  |  |  |  |  | Chinese
工业催化 Current Issue | Next Issue | Archive | Adv Search  |  Next Articles  
Catalytic hydro-chlorination of acetylene:analysis and improvement of non-mercuric homogenous system
HUO Yupeng,LUO Qin,YANG Qin,JIANG Wenwei,LUO Yun
School of Chemical Engineering,Sichuan University;Chengdu Huien Fine Chemical Co. Ltd.;Yibin Tianyuan Co.,Ltd.
 Download: PDF (0 KB)   HTML (0 KB)   Export: BibTeX | EndNote (RIS)      Supporting Info
Abstract A non-mercuric homogenous system for hydro-chlorination of acetylene,which comprised PtCl4,81-R and 1-chlorododecane was prepared. The system was characterized by using Fourier transform infrared spectroscopy and ultraviolet-visible spectroscopy. The active component was the ion-association complex [PtCl6]2-[RNH3]2+,and the reaction mechanism on this catalyst system was proposed. The performance of different applications with multiple catalyst promoters was compared through orthogonal experiments. The results showed that when the concentration of Pt+ was 0.005mol/L,the average conversion in the first 20 hours could be more than 80%,with the selectivity above 99%.
Service
E-mail this article mercury free catalystsethane hydrochloridehomogeneous activated systemchloroethylene”. Please open it by linking:" name=neirong>
Add to my bookshelf
Add to citation manager
E-mail Alert
RSS
Articles by authors
Key words:   
Cite this article:   
. Catalytic hydro-chlorination of acetylene:analysis and improvement of non-mercuric homogenous system[J]. , 2009, 28(7): 1182-.
URL:  
http://www.hgjz.com.cn/EN/     or     http://www.hgjz.com.cn/EN/Y2009/V28/I7/1182
 
No references of article
No Similar of article
CopyRight © 2012 Editor By SPACECRAFT RECOVERY & REMOTE SENSING
Support By Beijin Magtech