过硫酸盐高级氧化降解水体中有机污染物研究进展

黄智辉; 纪志永; 陈希; 郭小甫; 王士钊; 袁俊生

doi:10.16085/j.issn.1000-6613.2018-1576

您当前的位置：

首页 >

文章列表页 >

过硫酸盐高级氧化降解水体中有机污染物研究进展

资源与环境化工 | 更新时间：2020-06-24

- 过硫酸盐高级氧化降解水体中有机污染物研究进展
- Degradation of organic pollutants in water by persulfate advanced oxidation
- 化工进展 2019年第5期页码：2461-2470
- 作者机构：
  
  1.河北工业大学化工学院，化工节能过程集成与资源利用国家-地方联合工程实验室，天津 300130
  2.河北工业大学化工学院，海水资源高效利用化工技术教育部工程研究中心，天津 300130
  3.河北省现代海洋化工技术协同创新中心，天津 300130
- 作者简介：
  
  黄智辉（1993—），男，博士研究生，研究方向为环境化学。E-mall：cmhzh@163.com。
  纪志永，教授，博士生导师，研究方向为溶存化学资源分离与纯化及环境保护。E-mall：jizhiyong@hebut.edu.cn。
- 基金信息：
  
  国家重点研发计划(2016YFB0600504);河北省研究生创新资助项目(CXZZSS2017042)
- DOI：10.16085/j.issn.1000-6613.2018-1576
  中图分类号： X131.2;X52;TQ031.7
- 收稿：2018-08-01，
  
  修回：2018-10-22，
- 稿件说明：
移动端阅览
黄智辉, 纪志永, 陈希, 等. 过硫酸盐高级氧化降解水体中有机污染物研究进展[J]. 化工进展, 2019, 38(5): 2461-2470.

HUANG Zhihui, JI Zhiyong, CHEN Xi, et al. Degradation of organic pollutants in water by persulfate advanced oxidation[J]. Chemical Industry and Engineering Progress, 2019, 38(5): 2461-2470.
黄智辉, 纪志永, 陈希, 等. 过硫酸盐高级氧化降解水体中有机污染物研究进展[J]. 化工进展, 2019, 38(5): 2461-2470. DOI： 10.16085/j.issn.1000-6613.2018-1576.

HUANG Zhihui, JI Zhiyong, CHEN Xi, et al. Degradation of organic pollutants in water by persulfate advanced oxidation[J]. Chemical Industry and Engineering Progress, 2019, 38(5): 2461-2470. DOI： 10.16085/j.issn.1000-6613.2018-1576.

摘要

基于硫酸根自由基（sulfate radical，SO

·）氧化原理的活化过硫酸盐（persulfate，PS）氧化法是近年来高级氧化工艺（advanced oxidation process，AOP）的研究热点，以经济、高效、环境友好、安全稳定的优势在水处理、环境保护等领域开辟了新的思路。此前，学者们发现过硫酸盐高级氧化根据活化反应条件（如温度、光照、pH、过渡金属及催化剂等）的不同，会产生不同的自由基参与氧化反应，对降解结果也会产生不同程度的影响。本文根据相关自由基氧化机理，从产生硫酸根自由基的单一氧化、复杂活化体系硫酸根自由基与其他自由基复合氧化以及强化降解等方面，分析了近几年国内外学者对过硫酸盐降解典型有机污染物的研究及在催化剂开发方面所做的工作，指出了许多新颖的过硫酸盐活化手段及其降解效果与不足，并就未来的发展进行了展望，以期为过硫酸盐氧化法未来更好地发展和应用探索出路。

Abstract

Activated persulfate (PS) oxidation based on the oxidation principle of sulfate radical (SO

·) is a hot research topic of advanced oxidation process (AOP) in recent years. Since activated persulfate oxidation is economical

efficient

environmentally friendly

safe and stable

it gives out new countermeasures in water treatment

environmental protection and other fields. Previously

scholars found that the activated persulfate oxidation had different free radicals involved in the oxidation reaction with different reaction conditions such as pH

catalysts

which lead to varying degrees of influence in degradation results. Based on the relevant radical oxidation mechanism

including single oxidation with sulfate radical

synergistic oxidation with sulfate radical and the other enhanced catalytic activation

the domestic and foreign scholars’ research on the degradation of typical organic pollutants by persulfate was analyzed. Besides

the work on catalyst development was studied

and many novel activated methods of persulfate and its degradation effect and deficiency were pointed out. Furthermore

the way out for better development and application of persulfate oxidation method in the future was explored.

关键词

Keywords

references

GLAZE W H . Drinking-water treatment with ozone [J ] . Environmental Science & Technology , 1987 , 21 ( 3 ): 224 - 230 .

张旋 , 王启山 . 高级氧化技术在废水处理中的应用 [J ] . 水处理技术 , 2009 , 35 ( 3 ): 24 - 28 .

ZHANG Xuan , WANG Qishan . Application of advanced oxidation technologies in wastewater treatment [J ] . Technology of Water Treatment , 2009 , 35 ( 3 ): 24 - 28 .

MARRONE P A , HONG G T . Corrosion control methods in supercritical water oxidation and gasification [J ] . The Journal of Supercritical Fluids , 2009 , 51 ( 2 ): 83 - 103 .

WANG J , WANG S . Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants [J ] . Chemical Engineering Journal , 2018 , 334 : 1502 - 1517 .

HOUSE D A . Kinetics and mechanism of oxidations by peroxydisulfate [J ] . Chemical Reviews , 1961 , 62 ( 3 ): 185 - 203 .

ANIPSITAKIS G P , DIONYSIOU D D . Transition metal/UV-based advanced oxidation technologies for water decontamination [J ] . Applied Catalysis B: Environmental , 2004 , 54 ( 3 ): 155 - 163 .

ANIPSITAKIS G P , DIONYSIOU D D . Radical generation by the interaction of transition metals with common oxidants [J ] . Environmental Science & Technology , 2004 , 38 ( 13 ): 3705 - 3712 .

NETA P , HUIE R E , ROSS A B . Rate constants for reactions of inorganic radicals in aqueous-solution [J ] . Journal of Physical & Chemical Reference Date , 1988 , 17 ( 3 ): 1027 - 1284 .

HOELDERICH W F , KOLLMER F . Oxidation reactions in the synthesis of fine and intermediate chemicals using environmentally benign oxidants and the right reactor system [J ] . Pure and Applied Chemistry , 2000 , 72 : 1273 - 1287 .

XU Z , SHAN C , XIE B , et al . Decomplexation of Cu(Ⅱ)-EDTA by UV/Persulfate and UV/H 2 O 2 : efficiency and mechanism [J ] . Applied Catalysis B: Environmental , 2016 , 200 : 439 - 447 .

KUSIC H , PETERNEL I , KOPRIVANAC N , et al . Ironactivated persulfate oxidation of an azo dye in model wastewater: influence of iron activator type on process optimization [J ] . Journal of Environmental Chemical Engineering , 2011 , 137 ( 6 ): 454 : 463 .

OH S Y , KANG S G , CHIU P C . Degradation of 2,4-dinitrotoluene by persulfate activated with zero-valent iron [J ] . Science of the Total Environment , 2010 , 408 ( 16 ): 3464 - 3468 .

LIANG C J , GUO Y Y . Mass transfer and chemical oxidation of naphthalene particles with zerovalent iron activated persulfate [J ] . Environmental Science & Technology , 2010 , 44 ( 21 ): 8203 - 8208 .

LE C , WU J H , LI P , et al . Decolorization of anthraquinone dye reactive blue 19 by the combination of persulfate and zero-valent iron [J ] . Water Science and Technology , 2011 , 64 ( 3 ): 754 - 759 .

HUSSAIN I , ZHANG Y , HUANG S , et al . Degradation of pchloroaniline by persulfate activated with zero-valent iron [J ] . Chemical Engineering Journal , 2012 , 203 : 269 - 276 .

XIONG X M , SUN B , ZHANG J , et al . Activating persulfate by Fe 0 coupling with weak magnetic field: performance and mechanism [J ] . Water Research , 2014 , 62 : 53 - 62 .

GIRIT B , DURSUN D , OLMEZHANCI T , et al . Treatment of aqueous bisphenol A using nano-sized zero-valent iron in the presence of hydrogen peroxide and persulfate oxidants .[J ] . Water Science & Technology , 2015 , 71 ( 12 ): 1859 - 1868 .

ARSLANALATON I , OLMEZHANCI T , GENÇ B , et al . Advanced oxidation of the commercial nonionic surfactant octylphenol polyethoxylate Triton™ X-45 by the persulfate/UV-C process: effect of operating parameters and kinetic evaluation [J ] . Frontiers in Chemistry , 2013 , 1 : 4 .

LIU C S , SHIH K , SUN C X , et al . Oxidative degradation of propachlor by ferrous and copper ion activated persulfate [J ] . Science of the Total Environment , 2012 , 416 : 507 - 512 .

吴丽颖 , 王炳煌 , 张圆春 , 等 . 凝胶球负载零价铁活化过硫酸盐降解偶氮染料废水 [J ] . 化工进展 , 2017 , 36 ( 6 ): 2318 - 2324 .

WU Liying , WANG Binghuang , ZHANG Yuanchun , et al . Degradation of Reactive Black 5 (RBK5) by gelatin balls loading iron activating sodium persulfate [J ] . Chemical Industry and Engineering Progress , 2017 , 36 ( 6 ): 2318 - 2324 .

WU Y , PRULHO R , BRIGANTE M , et al . Activation of persulfate by Fe(Ⅲ) species: implications for 4- tert -butylphenol degradation [J ] . Journal of Hazardous Materials , 2017 , 322 : 380 - 386 .

COPE V W , CHEN S N , Hoffman M Z . Intermediates in the photochemistry of of carbonato-amine complexes of cobalt(Ⅲ). Carbonate(-) radicals and the aquocarbonato complex [J ] . Journal of the American Chemical Society , 1973 , 95 ( 10 ): 3116 - 3121 .

LIN K A , LIN J , JOCHEMS A P . Oxidation of amaranth dye by persulfate and peroxymonosulfate activated by ferrocene [J ] . Journal of Chemical Technology & Biotechnology, 2017 , 92 : 163 – 172 .

TANC Q , FU D F , GAO N Y , et al . Kinetic degradation of chloramphenicol in water byUV/persulfate system [J ] . Journal of Photochemistry and Photobiology A: Chemistry , 2017 , 332 : 406 - 412 .

BENNEDSEN L R , MUFF J , SØGAARD E G . Influence of chloride and carbonates on the reactivity of activated persulfate [J ] . Chemosphere , 2012 , 86 ( 11 ): 1092 - 1097 .

DENG J , SHAO Y , GAO N , et al . Degradation of the antiepileptic drug carbamazepine upon different UV-based advanced oxidation processes in water [J ] . Chemical Engineering Journal , 2013 , 222 : 150 - 158 .

QIAN Y J , GUO X , ZHANG Y L , et al . Perfluorooctanoic acid degradation using UV-persulfate process: modeling of the degradation and chlorate formation [J ] . Environmental Science & Technology , 2016 , 50 : 772 - 781 .

FANG G , GAO J , DIONYSIOU D D , et al . Activation of persulfate by quinones: free radical reactions and implication forthe degradation of PCBs [J ] . Environmental Science & Technology , 2013 , 47 ( 9 ): 4605 - 4611 .

AHMAD M , TEEL A L , WATTS R J . Mechanism of persulfate activation by phenols [J ] . Environmental Science & Technology , 2013 , 47 ( 11 ): 5864 - 5871 .

GRACA C , VELOSA A C , TEIXEIRA A C . Amicarbazone degradation by UVA-activated persulfate in the presence of hydrogen peroxide or Fe 2+ [J ] . Catalysis Today , 2017 , 280 : 80 - 85 .

KEEN O S , LOVE N G , LINDEN K G . The role of effluent nitrate in trace organic chemical oxidation during UV disinfection [J ] . Water Research , 2012 , 46 ( 16 ): 5224 - 5234 .

LIANG C , WANG Z S , BRUELL C J . Influence of pH on persulfate oxidation of TCE at ambient temperatures [J ] . Chemosphere , 2007 , 66 ( 1 ): 106 - 113 .

PENNINGTON D E , HAIM A . Stoichiometry and mechanism of the chromium(Ⅱ)-peroxydisulfate reaction [J ] . Journal of the American Chemical Society , 1968 , 90 ( 14 ): 3700 - 3704 .

NORMAN R O C , STOREY P M , WEST P R . Electron spin resonance studies. Part http://notExist.jpg http://notExist.jpg http://notExist.jpg 5.75733376 3.04799986 . Reactions of the sulphate radical anion with organic compounds [J ] . Journal of the Chemical Society B: Physical Organic , 1970 : 1087 - 1095 .

HAYON E , TREININ A , WILF J . Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite-bisulfite-pyrosulfite systems. SO 2 - , SO 3 - , SO 4 - , and SO 5 - radicals [J ] . Journal of the American Chemical Society , 1972 , 94 ( 1 ): 47 - 57 .

BABU K A , SATHISH K P S , SAMBANDAM A , et al . Sonochemical degradation of Rhodamine B using oxidants, hydrogen peroxide/peroxydisulfate/peroxymonosulfate, with Fe 2+ ion: proposed pathway and kinetics [J ] . Environmental Engineering Science , 2015 , 32 ( 2 ): 1 - 12 .

FANG G D , DIONYSIOU D D , WANG Y , et al . Sulfate radical-based degradation of polychlorinated biphenyls: effects of chloride ion and reaction kinetics .[J ] . Journal of Hazardous Materials , 2012 , 227 / 228 ( 43 ): 394 - 401 .

ISMAIL L , FERRONATO C , FINE L , et al . Elimination of sulfaclozine from water with SO 4 ·- radicals: evaluation of different persulfate activation methods [J ] . Applied Catalysis B: Environmental , 2016 , 201 : 573 - 581 .

DING D , LIU C , JI Y , et al . Mechanism insight of degradation of norfloxacin by magnetite nanoparticles activated persulfate: identification of radicals and degradation pathway [J ] . Chemical Engineering Journal , 2017 , 308 : 330 - 339 .

FANG G , WU W , LIU C , et al . Activation of persulfate with vanadium species for PCBs degradation: a mechanistic study [J ] . Applied Catalysis B: Environmental , 2016 , 202 : 1 - 11 .

GAO Y , LI S , LI Y , et al . Accelerated photocatalytic degradation of organic pollutant over metal-organic framework MIL-53(Fe) under visible LED light mediated by persulfate [J ] . Applied Catalysis B: Environmental , 2017 , 202 : 165 - 174 .

AHMAD M . Innovative oxidation pathways for the treatment of traditional and emerging contaminants [D ] . Washington : Washington State University , 2012 .

ZHANG Y , TRAN H P , HUSSAIN I , et al . Degradation of p -chloroaniline by pyrite in aqueous solutions [J ] . Chemical Engineering Journal , 2015 , 279 : 396 - 401 .

ZHANG Y , TRAN H P , DU X , et al . Efficient pyrite activating persulfate process for degradation of p -chloroaniline in aqueous systems: a mechanistic study [J ] . Chemical Engineering Journal , 2017 , 308 : 1112 - 1119 .

LIU M , HOU L , LI Q , et al . Heterogeneous degradation of tetracycline by magnetic Ag/AgCl/modified zeolite X–persulfate system under visible light [J ] . RSC Advances , 2016 , 6 ( 42 ): 35216 - 35227 .

ESKANDARIAN M R , FAZLI M , RASOULIFARD M H , et al . Decomposition of organic chemicals by zeolite-TiO 2 , nanocomposite supported onto low density polyethylene film under UV-LED powered by solar radiation [J ] . Applied Catalysis B: Environmental , 2016 , 183 : 407 - 416 .

FERKOUS H , MEROUANI S , HAMDAOUI O , et al . Persulfate-enhanced sonochemical degradation of naphthol blue black in water: evidence of sulfate radical formation .[J ] . Ultrasonics Sonochemistry , 2016 , 34 : 580 - 587 .

ARSLAN-ALATON I , OLMEZ-HANCI T , KHOEI S , et al . Oxidative degradation of Triton X-45 using zero valent aluminum in the presence of hydrogen peroxide, persulfate and peroxymonosulfate [J ] . Catalysis Today , 2017 , 280 : 199 - 207 .

PENG H , ZHANG W , LIU L , et al . Degradation performance and mechanism of decabromodiphenyl ether (BDE209) by ferrous-activated persulfate in spiked soil [J ] . Chemical Engineering Journal , 2016 , 307 : 750 - 755 .

CAI J , ZHOU M , YANG W , et al . Degradation and mechanism of 2,4-dichlorophenoxyacetic acid (2,4-D) by thermally activated persulfate oxidation [J ] . Chemosphere , 2018 , 212 : 784 - 793 .

GAO H , CHEN J , ZHANG Y , et al . Sulfate radicals induced degradation of Triclosan in thermally activated persulfate system [J ] . Chemical Engineering Journal , 2016 , 306 : 522 - 530 .

WANG Z , YUAN R , GUO Y , et al . Effects of chloride ions on bleaching of azo dyes by Co 2+ /oxone reagent: kinetic analysis [J ] . Journal of Hazardous Materials , 2011 , 190 ( 1 / 2 / 3 ): 1083 - 1087 .

FAN Y , JI Y , KONG D , et al . Kinetic and mechanistic investigations of the degradation of sulfamethazine in heat-activated persulfate oxidation process [J ] . Journal of Hazardous Materials , 2015 , 300 : 39 - 47 .

PENG H , ZHANG W , XU L , et al . Oxidation and mechanism of decabromodiphenyl ether (BDE209) by thermally activated persulfate (TAP) in a soil system [J ] . Chemical Engineering Journal , 2016 , 306 : 226 - 232 .

NIE M , YANG Y , ZHANG Z , et al . Degradation of chloramphenicol by thermally activated persulfate in aqueous solution [J ] . Chemical Engineering Journal , 2014 , 246 : 373 - 382 .

TAN C , GAO N , YANG D , et al . Degradation of antipyrine by UV, UV/H 2 O 2 and UV/PS [J ] . Journal of Hazardous Materials , 2013 , 260 ( 18 ): 1008 - 1016 .

JAFARI A J , KAKAVANDI B , JAAFARZADEH N , et al . Heterogeneous Fenton-like catalytic oxidation of tetracycline by AC@Fe 3 O 4 as a heterogeneous persulfate activator: adsorption and degradation studies [J ] . Journal of Industrial & Engineering Chemistry , 2017 , 45 : 323 - 333 .

DUAN X , SUN H , KANG J , et al . Insights into heterogeneous catalysis of persulfate activation on dimensional-structured nanocarbons [J ] . ACS Catalysis , 2015 , 5 : 4629 - 4636 .

DUAN X , SU C , ZHOU L , et al . Surface controlled generation of reactive radicals from persulfate by carbocatalysis on nanodiamonds [J ] . Applied Catalysis B: Environmental , 2016 , 194 : 7 - 15 .

CELYNA K O , WASIU A L , PRINCE A N , et al . Degradation of PFOA by hydrogen peroxide and persulfate activated by iron-modified diatomite [J ] . Applied Catalysis B: Environmental , 2016 , 192 : 253 - 259 .

HORI H , HAYAKAWA E , EINAGA H , ET AL . Decomposition of environmentally persistent perfluorooctanoic acid in water by photochemical approaches [J ] . Environmental Science & Technology , 2004 , 38 ( 22 ): 6118 - 6124 .

LIOU J S C , SZOSTEK B , DERITO C M , et al . Investigating the biodegradability of perfluorooctanoic acid [J ] . Chemosphere , 2010 , 80 ( 2 ): 176 - 183 .

SMITH B A , TEEL A L , WATTS R J . Identification of the reactive oxygen species responsible for carbon tetrachloride degradation in modified Fenton's systems [J ] . Environmental Science & Technology , 2004 , 38 ( 20 ): 5465 - 5469 .

LIU C M , DIAO Z H , HUO W Y , et al . Simultaneous removal of Cu 2+ and bisphenol A by a novel biochar-supported zero valent iron from aqueous solution: Synthesis, reactivity and mechanism [J ] . Environmental Pollution , 2018 , 239 : 698 - 705 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

微波协同高级氧化技术修复有机污染土壤的研究进展

基于尖晶石型CoFe2O4高级氧化降解水中有机污染物研究进展

共价有机框架材料在环境修复领域中吸附有机污染物的研究进展

碳量子点修饰半导体复合光催化剂降解水中有机污染物

活化过硫酸盐高级氧化法降解抗生素的研究进展