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1.昆明冶金职业大学建筑工程学院,云南 昆明 650033
2.废弃物资源化利用与新材料制备协同创新中心, 云南 昆明 650033
3.云南化钧新材料科技有限公司,云南 昆明 650033
4.云南巧消渣科技有限公司, 云南 昆明 650033
徐兴卫(1979—)男,硕士,副教授,研究方向为废弃物资源化利用。E-mail:276308990@qq.com。
李燕,副教授,研究方向为建筑工程技术。E-mail:28361761@qq.com。
收稿:2026-01-13,
修回:2026-04-16,
纸质出版:2026-08-25
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徐兴卫, 马宏彪, 肖丹丹, 等. 铜尾矿渣资源综合利用研究进展[J]. 化工进展, 2026, 45(8): 4995-5013.
XU Xingwei, MA Hongbiao, XIAO Dandan, et al. Research progress on comprehensive utilization of copper tailings resources[J]. Chemical Industry and Engineering Progress, 2026, 45(8): 4995-5013.
徐兴卫, 马宏彪, 肖丹丹, 等. 铜尾矿渣资源综合利用研究进展[J]. 化工进展, 2026, 45(8): 4995-5013. DOI: 10.16085/j.issn.1000-6613.2026-0055.
XU Xingwei, MA Hongbiao, XIAO Dandan, et al. Research progress on comprehensive utilization of copper tailings resources[J]. Chemical Industry and Engineering Progress, 2026, 45(8): 4995-5013. DOI: 10.16085/j.issn.1000-6613.2026-0055.
铜尾矿渣是天然铜矿石在开采、破碎、分选过程中产生的粉状或砾石状工业固体废物,其中含有大量的氧化钙、氧化铝和氧化硅等。随着工业化需求的不断升级,铜尾矿大量堆积。这些尾矿对环境管理和安全构成了严重威胁,威胁着生态系统和周边环境。针对这一问题,铜尾矿的大规模和可持续利用已成为矿区节约资源和保护环境的关键措施。本文首先介绍了铜尾矿渣的物理、化学性质以及矿物组成,明确了硫化铜矿尾矿与氧化铜矿尾矿两类尾矿的环境行为差异,进而梳理了全球主要国家和地区铜尾矿渣的分布特点与利用现状。在此基础上,综述了铜尾矿渣在建材领域、有价金属回收、土壤改良、污染治理等方面的应用进展,总结了其存在的技术问题与限制因素,并针对性地提出了建议,还对未来的发展前景进行了展望。提出应加强技术创新,拓宽铜尾矿渣的多元化和高附加值应用;指出多技术耦合综合回收有价资源、用作特种工程材料和高性能功能材料等是未来铜尾矿渣综合利用的重要发展方向。
Copper tailings are powdery or gravel-like industrial solid wastes generated during the mining
crushing
separation of natural copper ores containing substantial amounts of calcium oxide
aluminum oxide and silicon dioxide. The escalating demands of industrialization have led to the massive accumulation of these tailings. Consequently
this accumulation poses severe threat to environmental management and safety
threatening local ecosystems and the surrounding environment. To address this issue
the large-scale and sustainable utilization of copper tailings has emerged as a critical measure for resource conservation and environmental protection in mining areas. This paper first introduced the physical and chemical properties as well as the mineral composition of copper tailings. It clarified the differences in environmental behavior between sulfide copper tailings and oxide copper tailings
and subsequently reviewed the distribution characteristics and current utilization status of copper tailings across major countries and regions globally. Building upon this foundation
the paper comprehensively reviewed the application progress of copper tailings in fields such as building materials
valuable metal recovery
soil amelioration and pollution control. It also summarized the existing technical challenges and limiting factors
provided targeted recommendations
and forecasted future development prospects. The study emphasized that technological innovation should be strengthened to broaden the diversified and high-value-added applications of copper tailings. Furthermore
it identified that the comprehensive recovery of valuable resources through multi-technology coupling
along with their utilization as special engineering materials and high-performance functional materials
represented the pivotal direction for the future comprehensive utilization of copper tailings.
ADRIANTO Lugas Raka , PFISTER Stephan , HELLWEG Stefanie . Regionalized life cycle inventories of global sulfidic copper tailings [J ] . Environmental Science & Technology , 2022 , 56 ( 7 ): 4553 - 4564 .
DROBE Malte , HAUBRICH Frank , GAJARDO Mariano , et al . Processing tests, adjusted cost models and the economies of reprocessing copper mine tailings in Chile [J ] . Metals , 2021 , 11 ( 1 ): 103 .
CACCIUTTOLO Carlos , CANO Deyvis . Environmental impact assessment of mine tailings spill considering metallurgical processes of gold and copper mining: Case studies in the Andean countries of Chile and Peru [J ] . Water , 2022 , 14 ( 19 ): 3057 .
汪岚玢 . 铜尾渣的性质与资源化利用研究 [D ] . 武汉 : 中南民族大学 , 2024 .
WANG Lanfen . Research on the properties and resource utilization of copper slag [D ] . Wuhan : South-central University for Nationalities , 2024
CHEN Sungching , GAO Mengyao , LIN Weiting , et al . Study on the performance of highly doped copper tailings sand for concrete pavements using specific grading techniques [J ] . Minerals Engineering , 2024 , 216 : 108836 .
CHEN Sungching , GAO Mengyao , LIN Weiting , et al . Effects of incorporating large quantities of copper tailings with various particle sizes on the strength and pore structure of cement-based materials [J ] . Construction and Building Materials , 2022 , 329 : 127150 .
武志红 , 彭静之 , 潘悦鑫 , 等 . 铜尾矿在水泥生产及混凝土应用中的研究进展 [J ] . 硅酸盐通报 , 2025 , 44 ( 6 ): 2172 - 2180, 2192 .
WU Zhihong , PENG Jingzhi , PAN Yuexin , et al . Research progress of copper tailings in cement production and concrete application [J ] . Bulletin of the Chinese Ceramic Society , 2025 , 44 ( 6 ): 2172 - 2180, 2192 .
李冠男 , 王鑫鹏 , 武迪 , 等 . 基于正交实验铜尾矿-铅锌尾矿制备骨料研究 [J ] . 青岛理工大学学报 , 2025 , 46 ( 2 ): 32 - 39 .
LI Guannan , WANG Xinpeng , WU Di , et al . Study on the preparation of aggregate from copper tailings-lead-zinc tailings based on orthogonal experiment [J ] . Journal of Qingdao University of Technology , 2025 , 46 ( 2 ): 32 - 39 .
LI Chaofan , CAI Haoxuan , LIU Yuqing . Sustainable approaches to tailings remediation: Role of organic fertilizers [J ] . Environmental Research , 2025 , 276 : 121454 .
RUIZ-SÁNCHEZ A , TAPIA Julio C Juárez , LAPIDUS G T . Evaluation of acid mine drainage (AMD) from tailings and their valorization by copper recovery [J ] . Minerals Engineering , 2023 , 191 : 107979 .
PUNIA Anita . Role of temperature, wind, and precipitation in heavy metal contamination at copper mines: A review [J ] . Environmental Science and Pollution Research , 2021 , 28 ( 4 ): 4056 - 4072 .
LI Wei , DENG Yu , WANG Hao , et al . Potential risk, leaching behavior and mechanism of heavy metals from mine tailings under acid rain [J ] . Chemosphere , 2024 , 350 : 140995 .
KOUCHAM M’hamed , KHALIL Abdessamad , MOUHAGIR Lahcen , et al . Comprehensive assessment of environmental behavior of mine tailings for sustainable waste management and mitigation of pollution risks [J ] . Water , 2024 , 17 ( 1 ): 43 .
YIIKA Lemnyuy Prosper , TITA Margaret Awah , SUH Cheo Emmanuel , et al . Heavy metal speciation by tessier sequential extraction applied to artisanal gold mine tailings in eastern Cameroon [J ] . Chemistry Africa , 2023 , 6 ( 5 ): 2705 - 2723 .
WEI Linsheng , XU Hongxiang , WU Jin , et al . A review of research progress on the resource utilization of copper tailing [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 ( 3 ): 116238 .
SINGO N K , KRAMERS J D . Retreatability analysis of the Musina copper mine tailings in South Africa: An exploratory study [J ] . SN Applied Sciences , 2020 , 2 ( 10 ): 1707 .
潘美晨 , 穆攀攀 , 张晓光 . 铜尾矿资源化利用现状: 技术、问题和挑战 [J ] . 中国矿业 , 2025 , 34 ( 7 ): 42 - 55 .
PAN Meichen , MU Panpan , ZHANG Xiaoguang . Current status of copper tailings resource utilization: Technology, problems and challenges [J ] . China Mining Magazine , 2025 , 34 ( 7 ): 42 - 55 .
ZHENG Zhengqi , TAN Hongbo , HE Xingyang , et al . Physical-chemical characterization and application research of copper tailings with wet-grinding activation for use as supplementary cementitious material [J ] . Construction and Building Materials , 2025 , 489 : 142077 .
CHEN Sungching , GAO Mengyao , LIN Weiting , et al . Strength and microstructural development in concrete pavements by blended copper tailings powder and copper tailings sand [J ] . Materials Today Communications , 2024 , 41 : 110933 .
JIN Yingsheng , SUN Wei , PENG Jian , et al . Recovering the coarse particles associated with copper tailings by a new fluidized flotation column [J ] . Minerals Engineering , 2025 , 227 : 109305 .
YI Yuanrong , JAABAY Dina , LI Chunhui , et al . Study on the gelation performance of mechanically wet-activated copper tailings [J ] . Environmental Science and Pollution Research , 2025 , 32 ( 9 ): 5320 - 5331 .
PENG Zhiyuan , LIU Can , FU Yuhang , et al . Utilization of algal biochar for biopassivation of copper sulfide tailings to reduce acid mine drainage [J ] . Biology , 2025 , 14 ( 3 ): 300 .
ZUO Jianfen , LIN Yichao , XIE Xin , et al . Effect of plant growth and organic matter improvement on substrate properties and microbial community structure in copper tailings [J ] . Ecological Engineering , 2025 , 219 : 107649 .
LOYOLA Estefanía , SHAIKH Faiz , VARGAS Felipe . Effect of water as an alkali activator transport medium and other manufacturing factors in alkali activated copper mine tailings [J ] . Construction and Building Materials , 2025 , 465 : 140189 .
WANG Hongqian , PENG Huiling , WANG Yuan , et al . The high-efficiency and harmless utilization of steel slag/Dexing copper mine tailing: An environment-friendly permeable ceramic material with excellent permeability [J ] . JOM , 2025 , 77 ( 12 ): 9500 - 9511 .
PAN Zhenbei , WANG Qikun , WANG Hongqian , et al . Crystallization, structure-property evolution, and solidification of heavy metals of glass-ceramics based on copper tailing/coal slag/red mud [J ] . Journal of Non-Crystalline Solids , 2024 , 646 : 123263 .
KARPPINEN Anssi , SEISKO Sipi , LUNDSTRÖM Mari . Atmospheric leaching of Ni, Co, Cu, and Zn from sulfide tailings using various oxidants [J ] . Minerals Engineering , 2024 , 207 : 108576 .
BOTELHO JUNIOR Amilton Barbosa , DREISINGER David B , ESPINOSA Denise C R . A review of nickel, copper, and cobalt recovery by chelating ion exchange resins from mining processes and mining tailings [J ] . Mining , Metallurgy & Exploration, 2019 , 36 ( 1 ): 199 - 213 .
朱海东 . 铜矿尾砂制备免烧砖重金属浸出规律及其风险评价 [D ] . 淮南 : 安徽理工大学 , 2025 .
ZHU Haidong . Heavy metal leaching law and risk assessment of non-fired bricks prepared from copper tailings [D ] . Huainan : Anhui University of Science & Technology , 2025 .
赵陈龙 , 周世跃 , 陶燕蓝 . 某铜尾矿堆渣场重金属污染特征与风险评价 [J ] . 有色金属(冶炼部分) , 2025 ( 5 ): 181 - 193 .
ZHAO Chenlong , ZHOU Shiyue , TAO Yanlan . Pollution characterization and risk assessment of heavy metal in a copper tailings slag dump [J ] . Nonferrous Metals (Extractive Metallurgy) , 2025 ( 5 ): 181 - 193 .
ZENG Hang , RAMANATHAN Sivakumar , KIM Hee Jeong . Effect of copper mine tailings and copper slag on the hydration, microstructure, and mechanical property in Portland cement [J ] . Results in Engineering , 2025 , 26 : 104890 .
施麟芸 , 徐玉华 , 匡敬忠 , 等 . 不同粒级铜尾矿对CaO-MgO-Al 2 O 3 -SiO 2 微晶玻璃析晶性能的影响 [J ] . 材料科学与工程学报 , 2024 , 42 ( 3 ): 387 - 393 .
SHI Linyun , XU Yuhua , KUANG Jingzhong , et al . Effect of copper tailings with different sizes on crystallization properties of CaO-MgO-Al 2 O 3 -SiO 2 glass-ceramics [J ] . Journal of Materials Science and Engineering , 2024 , 42 ( 3 ): 387 - 393 .
傅开彬 , 李贺 , 付华洪 , 等 . 四川里伍铜尾矿中铁闪锌矿和磁黄铁矿的高效分离回收试验 [J ] . 金属矿山 , 2024 ( 6 ): 123 - 129 .
FU Kaibin , LI He , FU Huahong , et al . Experiment on efficient separation and recovery of marmatite and pyrrhotite from liwu copper tailings in Sichuan [J ] . Metal Mine , 2024 ( 6 ): 123 - 129 .
ANASTASSAKIS Georgios N , BEVILACQUA Paolo , DE LORENZI Lorenzo . Recovery of residual copper from low-content tailings derived from waste electrical cable treatment [J ] . International Journal of Mineral Processing , 2015 , 143 : 105 - 111 .
LUO Bing , PENG Tongjiang , SUN Hongjuan . Recovery of γ-Fe 2 O 3 from copper ore tailings by magnetization roasting and magnetic separation [J ] . Open Chemistry , 2021 , 19 ( 1 ): 128 - 137 .
NAKHAEI Fardis , ALAGHA Lana , WYSS Gary . Unlocking the potential of copper sulfide tailings as a secondary source for tellurium and precious metals: A comprehensive characterization study [J ] . Cleaner Engineering and Technology , 2025 , 29 : 101081 .
BAI Xiukui , NONG Yubo , LIN Hua , et al . Effects of carboxyl-modified copper tailings on the hydration behavior and microstructure of cement [J ] . Construction and Building Materials , 2025 , 492 : 143065 .
唐培垚 , 史伟强 , 陈先万 , 等 . 铜尾矿焙烧活化制备硅基土壤调理剂技术及机理研究 [J ] . 铜业工程 , 2025 ( 5 ): 104 - 114 .
TANG Peiyao , SHI Weiqiang , CHEN Xianwan , et al . Fabrication technology and mechanism of silicon-based soil conditioner pre-pared by combustion and activation of copper tailings [J ] . Copper Engineering , 2025 ( 5 ): 104 - 114 .
袁鹏 . 安徽某地铜尾矿资源的综合利用研究 [J ] . 矿业工程 , 2023 , 21 ( 2 ): 61 - 65 .
YUAN Peng . Study on comprehensive utilization of copper tailings resources in a place in Anhui Province [J ] . Mining Engineering , 2023 , 21 ( 2 ): 61 - 65 .
LAN Jirong , HOU Haobo , DAI Jianguo . Optimizing waste alkali activation of aqueous-solid waste through convection-enhanced homogeneous mixing for cementitious material synthesis [J ] . Chemical Engineering Journal , 2025 , 520 : 166257 .
WU Zhihong , PAN Yuexin , WANG Jiawei , et al . Effect and mechanism analysis of phosphate on the enhancement of copper tailings activity [J ] . Journal of Materials in Civil Engineering , 2025 , 37 ( 12 ): 04025444 .
REYES-ROMÁN Arturo , SAMARINA Tatiana , CASTILLO-GODOY Daniza , et al . Use of abandoned copper tailings as a precursor to the synthesis of fly-ash-based alkali activated materials [J ] . Materials , 2025 , 18 ( 17 ): 3926 .
吴培喜 . 选铜尾矿基地质聚合物性能及机理研究 [D ] . 深圳 : 深圳大学 , 2025 .
WU Peixi . Study on the properties and mechanism of geopolymer from copper tailings [D ] . Shenzhen : Shenzhen University , 2025 .
WANG Wei , WEI Pengfei , JIANG Ping , et al . Composite geopolymer based on copper tailings: Mechanical properties, strength models and microstructure [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 ( 3 ): 117112 .
PENG Jingzhi , WU Zhihong , PAN Yuexin , et al . Enhancing the hydration properties of copper tailings cement through improving the interfacial transition zone by calcium-based activators [J ] . Minerals Engineering , 2025 , 232 : 109542 .
PEI Tianrui , ZHENG Yan , WANG Yali , et al . Utilization of copper tailings in the preparation of low-calcium Portland cement clinker and carbonation-hardening mechanism [J ] . Construction and Building Materials , 2024 , 457 : 139362 .
吴然圆 , 孙大定 , 许庆虎 , 等 . 钙硅比对铜尾矿蒸压加气混凝土的影响 [J ] . 金属矿山 , 2025 ( 10 ): 273 - 278 .
WU Ranyuan , SUN Dading , XU Qinghu , et al . Effect of calcium-silicon ratio on autoclaved aerated concrete with copper tailings [J ] . Metal Mine , 2025 ( 10 ): 273 - 278 .
LI Haizhou , ZHANG Lu , LIU Jianping , et al . Optimization of the proportioning and microscopic mechanism study of cement mortar prepared with copper tailings as fine aggregate [J ] . Materials , 2025 , 18 ( 11 ): 2569 .
WU Congcong , WANG Yonghui , TONG Chao . Study on the properties of copper tailings with diversified treatment in the preparation of low shrinkage and high strength mortar in hydraulic engineering [J ] . Results in Engineering , 2025 , 26 : 105551 .
钱振东 , 许子健 , 闵一桐 , 等 . 铜尾矿作沥青混合料填料的可行性与环境影响评估 [J ] . 长安大学学报(自然科学版) , 2025 , 45 ( 3 ): 17 - 25 .
QIAN Zhendong , XU Zijian , MIN Yitong , et al . Feasibility and environmental impact assessment of copper tailings as asphalt mixture filler [J ] . Journal of Chang’an University (Natural Science Edition) , 2025 , 45 ( 3 ): 17 - 25 .
AN Guangdong , LI Siyang , LI Zhaorui , et al . Development and performance evaluation of translucent concrete incorporating activated copper tailings as cementitious material [J ] . Applied Sciences , 2025 , 15 ( 18 ): 10228
CHOUDHARY Kailash , GILL Gourav , SANGWA Narpat Ram , et al . Utilising copper tailings as a sustainable alternative to conventional structural filling materials: LCA analysis [J ] . Built Environment Project and Asset Management , 2025 , 15 ( 3 ): 415 - 431 .
王有团 , 杨志强 , 李茂辉 , 等 . 金川铜尾渣粉对充填体强度的影响 [J ] . 中南大学学报(自然科学版) , 2015 , 46 ( 12 ): 4391 - 4397 .
WANG Youtuan , YANG Zhiqiang , LI Maohui , et al . Effect of Jinchuan copper slag on filling body strength [J ] . Journal of Central South University (Science and Technology) , 2015 , 46 ( 12 ): 4391 - 4397 .
CHEN Wei , YIN Shenghua , CHEN Xun , et al . Study on comprehensive utilization of tailings by using bioleaching and microbial-cementation [J ] . Case Studies in Construction Materials , 2023 , 18 : e02190 .
QIU Xiang , YAO Jie , HE Zhongming , et al . Research on the preparation and performance characteristics of activated copper tailings grouting material based on solid waste synergy [J ] . Journal of Cleaner Production , 2025 , 514 : 145739 .
付宏渊 , 姚杰 , 邱祥 . 铜尾矿改性水泥基地聚合物注浆材料性能与机理分析 [J ] . 中南大学学报(自然科学版) , 2024 , 55 ( 3 ): 1107 - 1119 .
FU Hongyuan , YAO Jie , QIU Xiang . Performance and mechanism analysis of copper tailings modified cement-based geopolymer grouting materials [J ] . Journal of Central South University (Science and Technology) , 2024 , 55 ( 3 ): 1107 - 1119 .
施麟芸 , 徐玉华 , 魏琦 . Fe 2 O 3 对铜尾矿基CaO-MgO-Al 2 O 3 -SiO 2 微晶玻璃析晶行为的影响 [J ] . 硅酸盐通报 , 2022 , 41 ( 11 ): 3844 - 3851 .
SHI Linyun , XU Yuhua , WEI Qi . Effect of Fe 2 O 3 on crystallization behavior of CaO-MgO-Al 2 O 3 -SiO 2 glass-ceramics based on copper tailings [J ] . Bulletin of the Chinese Ceramic Society , 2022 , 41 ( 11 ): 3844 - 3851 .
赵庆朝 , 朱阳戈 , 孙永升 , 等 . 铜尾矿基微晶玻璃非均匀析晶过程形核机制研究 [J ] . 有色金属(矿山部分) , 2023 , 75 ( 6 ): 156 - 162 .
ZHAO Qingchao , ZHU Yangge , SUN Yongsheng , et al . Nucleation mechanism of non-uniform crystallization process of copper tailings-based glass-ceramics [J ] . NONFERROUS METALS (Mining Section) , 2023 , 75 ( 6 ): 156 - 162 .
李伟光 , 林荣琪 , 宋厚彬 , 等 . 高硫铜尾矿制备多孔陶瓷材料及其孔结构性能研究 [J ] . 矿产保护与利用 , 2024 , 44 ( 2 ): 91 - 98 .
LI Weiguang , LIN Rongqi , SONG Houbin , et al . Preparation of porous ceramic materials from high-sulfur copper tailings and its pore structure properties [J ] . Conservation and Utilization of Mineral Resources , 2024 , 44 ( 2 ): 91 - 98 .
石译文 . 铜尾矿在多孔烧结制品中的应用研究 [D ] . 天津 : 天津城建大学 , 2020 .
SHI Yiwen . Application research of copper tailings in porous sintered products [D ] . Tianjin : Tianjin Chengjian University , 2020 .
JIN Quanbin , LIU Zhibin , LU Liangliang , et al . Experimental study on the properties of CMTs-incorporated geopolymers prepared at low temperatures [J ] . Journal of Southeast University (English Edition) , 2024 , 40 ( 3 ): 295 - 303 .
冯启明 , 王维清 , 张博廉 , 等 . 利用四川某铜矿尾矿制作轻质免烧砖的工艺研究 [J ] . 中国矿业 , 2010 , 19 ( 12 ): 90 - 92, 95 .
FENG Qiming , WANG Weiqing , ZHANG Bolian , et al . Research on techniques of lightweight baking-free brick made of copper mine tailings from Sichuan [J ] . China Mining Magazine , 2010 , 19 ( 12 ): 90 - 92, 95 .
AHMARI Saeed , ZHANG Lianyang . Production of eco-friendly bricks from copper mine tailings through geopolymerization [J ] . Construction and Building Materials , 2012 , 29 : 323 - 331 .
NIKVAR-HASSANI Arash , VASHAGHIAN Hamidreza , HODGES Renee , et al . Production of green bricks from low-reactive copper mine tailings: Chemical and mechanical aspects [J ] . Construction and Building Materials , 2022 , 324 : 126695 .
徐伟 , 鲁亚 , 刘松柏 , 等 . 碱激发-碳养护对铜尾矿固化砖的作用机理研究 [J ] . 硅酸盐通报 , 2023 , 42 ( 1 ): 188 - 195, 221 .
XU Wei , LU Ya , LIU Songbai , et al . Mechanism of copper tailings cured bricks by alkali activation-carbonated conservation [J ] . Bulletin of the Chinese Ceramic Society , 2023 , 42 ( 1 ): 188 - 195, 221 .
AHMARI Saeed , ZHANG Lianyang . Utilization of cement kiln dust (CKD) to enhance mine tailings-based geopolymer bricks [J ] . Construction and Building Materials , 2013 , 40 : 1002 - 1011 .
XU Wei , ZHANG Yuyue , YAN Jun , et al . Microstructure and properties of high-strength lightweight ceramsites customised with ultra-fine copper tailings [J ] . Construction and Building Materials , 2024 , 429 , 136433 .
岳东亭 . 利用污泥/赤泥/钢渣等固体废物制备新型多孔陶粒的膨胀机理研究 [D ] . 济南 : 山东大学 , 2014 .
YUE Dongting . Preparation of innovative porous ceramsite by sewage sludge, red mud and steel slag and the research of its expansion mechanism [D ] . Jinan : Shandong University , 2014 .
陈沁媛 , 闫一凡 , 赵振华 , 等 . 固废基陶粒重金属固化效果及产品性能的影响因素研究进展 [J ] . 硅酸盐通报 , 2025 , 44 ( 2 ): 515 - 530 .
CHEN Qinyuan , YAN Yifan , ZHAO Zhenhua , et al . Research progress on factors influencing heavy metal solidification effect and product performance of solid waste-based ceramsite [J ] . Bulletin of the Chinese Ceramic Society , 2025 , 44 ( 2 ): 515 - 530 .
张敬义 , 范锦鹏 , 刘晓明 , 等 . 烧结工艺对多孔氮化硅陶瓷显微结构和力学性能的影响 [J ] . 硅酸盐学报 , 2017 , 45 ( 6 ): 806 - 810 .
ZHANG Jingyi , FAN Jinpeng , LIU Xiaoming , et al . Effect of sintering process on microstructure and mechanical properties of silicon nitride [J ] . Journal of the Chinese Ceramic Society , 2017 , 45 ( 6 ): 806 - 810 .
吴瑞 . 以高钙固废为原料的SiO 2 -Al 2 O 3 -CaO系轻质陶粒的制备及烧结机理研究 [D ] . 西安 : 西安建筑科技大学 , 2024 .
WU Rui . Preparation and sintering mechanism of SiO 2 -Al 2 O 3 -CaO based lightweight ceramsite from high-calcium solid waste as raw material [D ] . Xi’an : Xi’an University of Architecture and Technology , 2024 .
崔建国 . 西藏典型尾矿基多孔陶粒的制备及除磷研究 [D ] . 拉萨 : 西藏大学 , 2024 .
CUI Jianguo . Preparation of typical tailings-based porous ceramsite and phosphorus removal in Tibet [D ] . Lasa : Tibet University , 2024 .
卢奇奇 . 锰渣复配铜尾矿制备高强陶粒及其性能研究 [D ] . 淮南 : 安徽理工大学 , 2025 .
LU Qiqi . Preparation of high-strength ceramsite from manganese slag compounded with copper tailings and performance research [D ] . Huainan : Anhui University of Science & Technology , 2025 .
陈涛 , 肖军辉 , 邹凯 , 等 . 含铁铜尾矿选冶联合分选提铁研究 [J ] . 矿冶工程 , 2022 , 42 ( 4 ): 55 - 59 .
CHEN Tao , XIAO Junhui , ZOU Kai , et al . Iron extraction from iron-bearing copper tailings by a combined process of beneficiation and metallurgy [J ] . Mining and Metallurgical Engineering , 2022 , 42 ( 4 ): 55 - 59 .
SILVA Ruberlan , SILVA José Maria , GUIMARÃES Lorena , et al . Selective process route to recover magnetite from chalcopyrite dam copper flotation tailings [J ] . Mining , Metallurgy & Exploration, 2022 , 39 ( 6 ): 2517 - 2528 .
HOU Pengcheng , GAO Peng , YUAN Shuai , et al . Efficient separation of iron and rare earths from low-grade complex polymetallic ores [J ] . ACS Omega , 2025 , 10 ( 7 ): 6965 - 6975 .
KUKKALA Prabhu Chand , KUMAR Shravan , NIRALA Akhileshwar , et al . Beneficiation of low-grade hematite iron ore fines by magnetizing roasting and magnetic separation [J ] . ACS Omega , 2024 , 9 ( 7 ): 7634 - 7642 .
JIAO Ruimin , XING Peng , WANG Chengyan , et al . Recovery of iron from copper tailings via low-temperature direct reduction and magnetic separation: Process optimization and mineralogical study [J ] . International Journal of Minerals, Metallurgy, and Materials , 2017 , 24 ( 9 ): 974 - 982 .
CENG Chao , WANG Huajun , HU Wentao , et al . Recovery of iron and copper from copper tailings by coal-based direct reduction and magnetic separation [J ] . Journal of Iron and Steel Research , International, 2017 , 24 ( 10 ): 991 - 997 .
CARDENIA Chiara , BALOMENOS Efthymios , PANIAS Dimitris . Iron recovery from bauxite residue through reductive roasting and wet magnetic separation [J ] . Journal of Sustainable Metallurgy , 2019 , 5 ( 1 ): 9 - 19 .
邵爽 , 邢鹏 , 张文娟 , 等 . 从选铜尾矿中选择性还原回收铁 [J ] . 工程科学学报 , 2019 , 41 ( 6 ): 741 - 747 .
SHAO Shuang , XING Peng , ZHANG Wenjuan , et al . Process of the selective reduction and recovery of iron from copper tailings [J ] . Chinese Journal of Engineering , 2019 , 41 ( 6 ): 741 - 747 .
RISTOVIĆ Ivica , ŠTYRIAKOVÁ Darina , ŠTYRIAKOVÁ Iveta , et al . Bioleaching process for copper extraction from waste in alkaline and acid medium [J ] . Minerals , 2022 , 12 ( 1 ): 100 .
SHI Guiming , ZHOU Yichao , YE Changbing . Leaching of a tailings from oxy-sulfur copper ore with sulfuric acid [J ] . IOP Conference Series: Earth and Environmental Science , 2018 , 199 ( 4 ): 042017 .
SANTANDER Mario , VALDERRAMA Luis . Recovery of pyrite from copper tailings by flotation [J ] . Journal of Materials Research and Technology , 2019 , 8 ( 5 ): 4312 - 4317 .
顾恒光 , 范宛惠 , 谢蕾 , 等 . 某高硫铜矿预选铜尾矿活化浮硫试验研究 [J ] . 中国矿业 , 2024 , 33 ( 7 ): 234 - 244 .
GU Hengguang , FAN Wanhui , XIE Lei , et al . Experimental study on activated sulfur flotation of pre-processed copper tailings from a high sulfur copper mine [J ] . China Mining Magazine , 2024 , 33 ( 7 ): 234 - 244 .
尹政道 , 王涵 , 申培伦 , 等 . 云南某铜炉渣中铜深度浮选回收试验研究 [J ] . 有色金属(选矿部分) , 2024 ( 12 ): 63 - 71 .
YIN Zhengdao , WANG Han , SHEN Peilun , et al . Experimental study on deep flotation recovery of copper from copper slag in Yunnan [J ] . Nonferrous Metals (Mineral Processing Section) , 2024 ( 12 ): 63 - 71 .
江锋 , 王鹏渊 , 温志森 , 等 . 西藏某铜金矿梯级浮选回收试验研究 [J ] . 矿冶工程 , 2025 , 45 ( 4 ): 58 - 62 .
JIANG Feng , WANG Pengyuan , WEN Zhisen , et al . Experimental study on stepwise flotation recovery of copper-gold ore from Xizang [J ] . Mining and Metallurgical Engineering , 2025 , 45 ( 4 ): 58 - 62 .
吴雨瑶 , 李广涛 , 简胜 , 等 . 低品位铜硫矿石混合浮选—分离铜硫 [J ] . 矿冶 , 2025 , 34 ( 2 ): 289 - 297 .
WU Yuyao , LI Guangtao , JIAN Sheng , et al . Separation of copper and sulfur from low-grade copper-sulfur ore by bulk flotation [J ] . Mining and Metallurgy , 2025 , 34 ( 2 ): 289 - 297 .
HANSEN Henrik K , YIANATOS Juan B , OTTOSEN Lisbeth M . Speciation and leachability of copper in mine tailings from porphyry copper mining: Influence of particle size [J ] . Chemosphere , 2005 , 60 ( 10 ): 1497 - 1503 .
ANTONIJEVIĆ M M , DIMITRIJEVIĆ M D , STEVANOVIĆ Z O , et al . Investigation of the possibility of copper recovery from the flotation tailings by acid leaching [J ] . Journal of Hazardous Materials , 2008 , 158 ( 1 ): 23 - 34 .
WANG Yijie , WEN Shuming , FENG Qicheng , et al . Leaching characteristics and mechanism of copper flotation tailings in sulfuric acid solution [J ] . Russian Journal of Non-Ferrous Metals , 2015 , 56 ( 2 ): 127 - 133 .
XIE Yanting , XU Yanbin , YAN Lan , et al . Recovery of nickel, copper and cobalt from low-grade Ni-Cu sulfide tailings [J ] . Hydrometallurgy , 2005 , 80 ( 1/2 ): 54 - 58 .
IBEBUNJO Kosisochi , EL OUARDI Youssef , BEDIAKO John Kwame , et al . Selective recovery of copper from copper tailings and wastewater using chelating resins with bis-picolylamine functional groups [J ] . Heliyon , 2024 , 10 ( 6 ): e27766 .
GAO Xiufang , JIANG Li , MAO Yilin , et al . Progress, challenges, and perspectives of bioleaching for recovering heavy metals from mine tailings [J ] . Adsorption Science & Technology , 2021 , 2021 : 9941979 .
CONIĆ Vesna , STANKOVIĆ Srđan , MARKOVIĆ Branislav , et al . Investigation of the optimal technology for copper leaching from old flotation tailings of the copper mine bor (Serbia) [J ] . Metallurgical and Materials Engineering , 2020 , 26 ( 2 ): 209 - 222 .
PEDERSEN Kristine B , JENSEN Pernille E , OTTOSEN Lisbeth M , et al . Metal speciation of historic and new copper mine tailings from Repparfjorden, Northern Norway, before and after acid, base and electrodialytic extraction [J ] . Minerals Engineering , 2017 , 107 : 100 - 111 .
HAN Baisui , ALTANSUKH Batnasan , HAGA Kazutoshi , et al . Development of copper recovery process from flotation tailings by a combined method of high‒pressure leaching‒solvent extraction [J ] . Journal of Hazardous Materials , 2018 , 352 : 192 - 203 .
ZHAPPAR Nariman K , SHAIKHUTDINOV Valentin M , KANAFIN Yerkanat N , et al . Bacterial and chemical leaching of copper-containing ores with the possibility of subsequent recovery of trace silver [J ] . Chemical Papers , 2019 , 73 ( 6 ): 1357 - 1367 .
LIU Yunjia , HUANG Longbin . Magnetite recovery from copper tailings increases arsenic distribution in solution phase and uptake in native grass [J ] . Journal of Environmental Management , 2017 , 186 : 175 - 182 .
BARRUETO Yahaira , IBÁÑEZ Juan Patricio , VELIZ Miguel , et al . Assessment of cobalt recovery from copper tailings by leaching with a choline chloride-citric acid deep eutectic solvent: Effects of pretreatment and oxidant use [J ] . Minerals , 2025 , 15 ( 11 ): 1187 .
MÄKINEN Jarno , SALO Marja , KHOSHKHOO Mohammad , et al . Bioleaching of cobalt from sulfide mining tailings; a mini-pilot study [J ] . Hydrometallurgy , 2020 , 196 : 105418 .
GUO Zhengqi , ZHU Deqing , PAN Jian , et al . Innovative methodology for comprehensive and harmless utilization of waste copper slag via selective reduction-magnetic separation process [J ] . Journal of Cleaner Production , 2018 , 187 : 910 - 922 .
陈肖汀 , 肖军辉 , 陈正义 , 等 . 响应曲面法优化含镍铜尾矿还原焙烧—磁选工艺提镍 [J ] . 金属矿山 , 2024 ( 4 ): 275 - 282 .
CHEN Xiaoting , XIAO Junhui , CHEN Zhengyi , et al . Optimization of nickel extraction from nickel-bearing copper tailings using reduction roasting-magnetic separation process with response surface methodology [J ] . Metal Mine , 2024 ( 4 ): 275 - 282 .
赵迎锋 , 邱廷省 , 陈江安 . 某选铜尾矿中白钨回收试验研究 [J ] . 矿产综合利用 , 2019 , 40 ( 3 ): 127 - 130 .
ZHAO Yingfeng , QIU Ting Xing , CHEN Jiang’an . Experimental study on tungsten recovery from the tailings produced by copper beneficiation [J ] . Multipurpose Utilization of Mineral Resources , 2019 , 40 ( 3 ): 127 - 130 .
WANG Jingkai , ZHANG Yafang , WU Jin , et al . Efficient recovery of tungsten from copper tailings using sodium carbonate synergistic pyrometallurgical smelting [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 ( 5 ): 118525 .
FALAGÁN Carmen , GRAIL Barry M , JOHNSON D Barrie . New approaches for extracting and recovering metals from mine tailings [J ] . Minerals Engineering , 2017 , 106 : 71 - 78 .
WANG Jieyi , SHEN Hairong , LI Mengke , et al . Sulfurization-derived Fe3S4 in copper tailings as a peroxymonosulfate activator for efficient salicylhydroxamic acid degradation [J ] . Chemical Engineering Journal , 2025 , 526 : 170913 .
SHEN Hairong , WANG Jieyi , LI Mengke , et al . Efficient aniline aerofloat degradation by oxygen vacancies-rich copper tailings/peroxymonosulfate system: Performance evaluation and active sites [J ] . Process Safety and Environmental Protection , 2025 , 196 : 106868 .
PAN Cong , SUN Yan , DONG Yiqie , et al . Efficient carbamazepine degradation by modified copper tailings and PMS system: Performance evaluation and mechanism [J ] . Journal of Hazardous Materials , 2024 , 465 : 133198 .
QU Chunlong , WANG Yachao , YU Kang , et al . Chemically modified copper tailings doped anti -UV ageing coating for flame retarding plywood through catalytic charring [J ] . Construction and Building Materials , 2024 , 425 : 135957 .
杨诗婕 . 西藏典型铜尾矿制备催化材料及其催化性能研究 [D ] . 拉萨 : 西藏大学 , 2024 .
YANG Shijie . Study on the preparation of catalytic materials from typical copper tailings in tibet and their catalytic performance [D ] . Lasa : Tibet University , 2024 .
TAO Lei , WANG Xueqian , WANG Langlang , et al . Efficient removal of sulfur dioxide from flue gas through liquid catalytic oxidation using copper tailing as the in situ iron ion donator [J ] . Energy & Fuels , 2020 , 34 ( 3 ): 3513 - 3521 .
TAO Lei , WANG Xueqian , NING Ping , et al . Removing sulfur dioxide from smelting flue and increasing resource utilization of copper tailing through the liquid catalytic oxidation [J ] . Fuel Processing Technology , 2019 , 192 : 36 - 44 .
MU Jing , HU Zhengyi , HUANG Lijuan , et al . Preparation of a silicon-iron amendment from acid-extracted copper tailings for remediating multi-metal-contaminated soils [J ] . Environmental Pollution , 2020 , 257 : 113565 .
LAZO Pamela , LAZO Andrea , HANSEN Henrik K , et al . Lead and copper removal from mine tailings using lycium chilense and haplopappus foliosus [J ] . Minerals , 2024 , 14 ( 3 ): 298 .
LI Ning , XIU Yubing , ZHANG Manyun , et al . Broussonetia papyrifera and biofertilizer synergy: Enhancing bacterial community stability and plant growth in copper tailings [J ] . Industrial Crops and Products , 2024 , 217 : 118793 .
黄玥娜 , 颜溪鸣 , 朱彬 , 等 . 微生物-植物联合修复对铜尾矿养分组成及重金属形态的影响 [J ] . 环境工程学报 , 2025 , 19 ( 7 ): 1703 - 1710 .
HUANG Yuena , YAN Ximing , ZHU Bin , et al . Effect of combined microbial-phytoremediation on nutrient composition and heavy metal morphology of copper tailings [J ] . Chinese Journal of Environmental Engineering , 2025 , 19 ( 7 ): 1703 - 1710 .
颜溪鸣 , 黄玥娜 , 杨顺富 , 等 . 有机酸淋洗和废菌棒添加对铜尾矿盆栽实验中养分和重金属的影响 [J ] . 环境工程学报 , 2025 , 19 ( 2 ): 446 - 456 .
YAN Ximing , HUANG Yuena , YANG Shunfu , et al . Effects of organic acid washing and edible fungi residue addition on nutrients and heavy metals in copper tailings potting experiments [J ] . Chinese Journal of Environmental Engineering , 2025 , 19 ( 2 ): 446 - 456 .
常道琴 , 宋乃平 , 岳健敏 , 等 . 微生物诱导碳酸钙沉淀对干旱半干旱区铜尾矿污染治理效果 [J ] . 水土保持学报 , 2022 , 36 ( 4 ): 365 - 374 .
CHANG Daoqin , SONG Naiping , YUE Jianmin , et al . Effect of microbial induced calcium carbonate precipitation on the pollution control of copper tailings in arid and semi -arid area [J ] . Journal of Soil and Water Conservation , 2022 , 36 ( 4 ): 365 - 374 .
YAO Aijun , WANG Yani , LING Xiaodan , et al . Effects of an iron-silicon material, a synthetic zeolite and an alkaline clay on vegetable uptake of as and Cd from a polluted agricultural soil and proposed remediation mechanisms [J ] . Environmental Geochemistry and Health , 2017 , 39 ( 2 ): 353 - 367 .
FISONGA Marsheal , JIANG Yun , DENG Tingting , et al . Strength performance and leachability of cement-stabilised copper tailings as land reclamation geomaterial for sustainable copper tailings disposal [J ] . Ain Shams Engineering Journal , 2025 , 16 ( 12 ): 103769 .
LIU Hong , TENG Yanguo , ZHENG Nengzhan , et al . Field experiments of phyto-stabilization, biochar-stabilization, and their coupled stabilization of soil heavy metal contamination around a copper mine tailing site, Inner Mongolia [J ] . Minerals , 2022 , 12 ( 6 ): 702 .
毛喆 , 杨涛涛 , 张金桃 , 等 . 基于铜尾矿生态化利用的矿山修复技术试验研究 [J ] . 地球环境学报 , 2024 , 15 ( 5 ): 790 - 798 .
MAO Zhe , YANG Taotao , ZHANG Jintao , et al . Research on mine remediation technology based on ecological utilization of copper tailings [J ] . Journal of Earth Environment , 2024 , 15 ( 5 ): 790 - 798 .
GARDNER Wendy C , NAETH M Anne , BROERSMA Klaas , et al . Influence of biosolids and fertilizer amendments on element concentrations and revegetation of copper mine tailings [J ] . Canadian Journal of Soil Science , 2012 , 92 ( 1 ): 89 - 102 .
SHU Junyu , WU Peiyu , XIE Xin , et al . Advancements in fertilizer conservation and ryegrass growth in high-altitude copper tailings regions: Facilitating green restoration and ensuring sustainable utilization [J ] . International Journal of Environmental Research , 2024 , 18 ( 6 ): 113 .
MONTOFRÉ Ítalo L , LAM Elizabeth J , RAMÍREZ Yendery , et al . Evaluation of copper tailing amendments through poultry waste and ammonium nitrate [J ] . Environmental Geochemistry and Health , 2021 , 43 ( 6 ): 2213 - 2230 .
卢红伶 , 陈法荣 , 蒋陈凯 , 等 . 不同桑树品种对铜尾矿土壤重金属积累转移特性比较 [J ] . 蚕业科学 , 2025 , 51 ( 5 ): 401 - 409 .
LU Honglin , CHEN Farong , JIANG Chenkai , et al . Comparative study on heavy metal accumulation and transfer characteristics in copper tailings soil among different mulberry varieties [J ] . Acta Sericologica Sinica , 2025 , 51 ( 5 ): 401 - 409 .
DENG Lijuan , YIN Min , YANG Shuanglin , et al . Assessment of metal residues in soil and evaluate the plant accumulation in copper mine tailings of Dongchuan, Southwest China [J ] . Frontiers in Plant Science , 2025 , 16 : 1528723 .
TOUCEDA-GONZÁLEZ M , ÁLVAREZ-LÓPEZ V , PRIETO-FERNÁNDEZ Á , et al . Aided phytostabilisation reduces metal toxicity, improves soil fertility and enhances microbial activity in Cu-rich mine tailings [J ] . Journal of Environmental Management , 2017 , 186 : 301 - 313 .
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