Preparation of F67/C@Z5 core-shell structure and its catalytic performance for guaiacol hydrodeoxygenation

PAN Yanning; MO Haoyuan; GU Yufei; WANG Wei; LI Zhixia

doi:10.16085/j.issn.1000-6613.2026-0256

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Preparation of F67/C@Z5 core-shell structure and its catalytic performance for guaiacol hydrodeoxygenation

更新时间：2026-04-30

- Preparation of F67/C@Z5 core-shell structure and its catalytic performance for guaiacol hydrodeoxygenation
- Chemical Industry and Engineering Progress (2026)
- 作者机构：
  
  1.广西大学化学化工学院，广西南宁 530004
  2.广西科学院，广西南宁 530007
- 作者简介：
- 基金信息：
- DOI：10.16085/j.issn.1000-6613.2026-0256
  CLC： TQ426.94
- Received：19 February 2026，
  
  Revised：2026-04-27，
- 稿件说明：
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PAN Yanning, MO Haoyuan, GU Yufei, et al. Preparation of F67/C@Z5 core-shell structure and its catalytic performance for guaiacol hydrodeoxygenation[J/OL]. Chemical Industry and Engineering Progress, 2026.
DOI：

PAN Yanning, MO Haoyuan, GU Yufei, et al. Preparation of F67/C@Z5 core-shell structure and its catalytic performance for guaiacol hydrodeoxygenation[J/OL]. Chemical Industry and Engineering Progress, 2026. DOI： 10.16085/j.issn.1000-6613.2026-0256.

摘要

木质素衍生酚类化合物的高效加氢脱氧是生物质资源化利用的关键步骤。采用静电逐层自组装策略，通过聚二烯二甲基氯化铵（PDDA）和聚苯乙烯磺酸钠（PSS）对ZSM-5分子筛表面进行电荷调控，成功在其表面均匀包覆ZIF-67壳层，经碳化及Ni负载后制备了核壳结构催化剂F67/C@Z5-Ni。采用XRD、FT-IR、SEM、TEM及XPS等手段对催化剂的物相结构、微观形貌及表面化学态进行表征，并以愈创木酚为模型化合物考察其加氢脱氧性能。Ni的引入使金属Co的电子密度升高，促进了金属-氮配位结构的形成，进一步提升了加氢活性。同时，氮掺杂碳壳层对金属纳米颗粒的限域作用有效抑制了反应过程中的金属烧结与流失，提升催化剂循环稳定性。结果表明，在反应温度250℃、氢压3 MPa、反应时间2 h的条件下，愈创木酚可实现完全转化，环己烷选择性高达92%。

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